Reactions of 1,2-propadienyl sulfides with aldehydes and acetals catalyzed by BF<inf>3</inf> · OEt<inf>2</inf>

Koichi Narasaka, Takanori Shibata, Yujiro Hayashi

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Abstract

Ene reaction proceeds between 1-alkyl-1,2-propadienyl sulfides and aldehydes in the presence of BF<inf>3</inf> · OEt<inf>2</inf> to afford 1,3-dienes possessing an alkylthio group. On the other hand, the reactions of 1-silyl-1,2-propadienyl sulfides with aldehydes or their dimethylacetals give aldol-type addition products, a-methylene acylsilanes.

Original languageEnglish
Pages (from-to)2825-2830
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume65
Issue number10
Publication statusPublished - 1992 Oct 1
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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