Reactions of allylic carbonates catalyzed by palladium, rhodium, ruthenium, molybdenum, and nickel complexes; allylation of carbonucleophiles and decarboxylation- dehydrogenation

Ichiro Minami, Isao Shimizu, Jiro Tsuji

    Research output: Contribution to journalArticle

    122 Citations (Scopus)

    Abstract

    Allylation of carbonucleophiles with allylic carbonates catalyzed by various transition metal complexes has been studied. Palladium, rhodium, ruthenium, nickel, and molybdenum complexes were found to be active catalysts. The rhodium catalyst showed a different regioselectivity from the other catalysts, the reaction can proceed without allylic rearrangement. In the absence of nucleophiles, allyl alkyl carbonates were converted into ketones by decarboxylation-dehydrogenation; the ruthenium catalyst was the most active in this reaction.

    Original languageEnglish
    Pages (from-to)269-280
    Number of pages12
    JournalJournal of Organometallic Chemistry
    Volume296
    Issue number1-2
    DOIs
    Publication statusPublished - 1985 Nov 26

    Fingerprint

    Allylation
    decarboxylation
    Rhodium
    Decarboxylation
    Molybdenum
    Ruthenium
    Carbonates
    Palladium
    Dehydrogenation
    dehydrogenation
    Nickel
    rhodium
    ruthenium
    molybdenum
    palladium
    carbonates
    nickel
    catalysts
    Catalysts
    Coordination Complexes

    ASJC Scopus subject areas

    • Biochemistry
    • Chemical Engineering (miscellaneous)
    • Inorganic Chemistry
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Science (miscellaneous)
    • Materials Chemistry

    Cite this

    Reactions of allylic carbonates catalyzed by palladium, rhodium, ruthenium, molybdenum, and nickel complexes; allylation of carbonucleophiles and decarboxylation- dehydrogenation. / Minami, Ichiro; Shimizu, Isao; Tsuji, Jiro.

    In: Journal of Organometallic Chemistry, Vol. 296, No. 1-2, 26.11.1985, p. 269-280.

    Research output: Contribution to journalArticle

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