Recent advances in iridium-catalyzed alkylation of C-H and N-H bonds

Shiguang Pan, Takanori Shibata

    Research output: Contribution to journalArticle

    184 Citations (Scopus)

    Abstract

    Over the past few years, iridium complexes have been widely used in the direct functionalization of unactivated bonds. In the presence of iridium catalysts, inactive C-H and N-H bonds have been transformed into C-C and N-C bonds in dehydrative alkylation using alcohols, allylation using allyl carbonates, and alkylation using alkenes. Enantioselective variants of some reactions have also been reported.

    Original languageEnglish
    Pages (from-to)704-712
    Number of pages9
    JournalACS Catalysis
    Volume3
    Issue number4
    DOIs
    Publication statusPublished - 2013 Apr 5

    Fingerprint

    Iridium
    Alkylation
    Allylation
    Carbonates
    Alkenes
    Olefins
    Alcohols
    Catalysts

    Keywords

    • alcohols
    • alkenes
    • alkylation
    • carbonates
    • iridium

    ASJC Scopus subject areas

    • Catalysis

    Cite this

    Recent advances in iridium-catalyzed alkylation of C-H and N-H bonds. / Pan, Shiguang; Shibata, Takanori.

    In: ACS Catalysis, Vol. 3, No. 4, 05.04.2013, p. 704-712.

    Research output: Contribution to journalArticle

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