Recent Advances of Biphenylene: Synthesis, Reactions and Uses

Hideaki Takano, Takeharu Ito, Stephen Kyalo Kanyiva, Takanori Shibata

Research output: Contribution to journal › Review article

Abstract

Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.

Original languageEnglish
JournalEuropean Journal of Organic Chemistry
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

Functional materials
Organometallics
Benzene
musculoskeletal system
Ligands
Catalysts
Molecules
synthesis
butadiene
spacers
reactivity
benzene
catalysts
ligands
rings
molecules
1,3-butadiene

Keywords

  • Biphenylene
  • C–C activation
  • Hydrocarbons
  • Metallacycles
  • Strained molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Recent Advances of Biphenylene : Synthesis, Reactions and Uses. / Takano, Hideaki; Ito, Takeharu; Kanyiva, Stephen Kyalo; Shibata, Takanori.

In: European Journal of Organic Chemistry, 01.01.2019.

Research output: Contribution to journal › Review article

Takano, H, Ito, T, Kanyiva, SK & Shibata, T 2019, 'Recent Advances of Biphenylene: Synthesis, Reactions and Uses', European Journal of Organic Chemistry. https://doi.org/10.1002/ejoc.201900111
Takano H, Ito T, Kanyiva SK, Shibata T. Recent Advances of Biphenylene: Synthesis, Reactions and Uses. European Journal of Organic Chemistry. 2019 Jan 1. https://doi.org/10.1002/ejoc.201900111
Takano, Hideaki ; Ito, Takeharu ; Kanyiva, Stephen Kyalo ; Shibata, Takanori. / Recent Advances of Biphenylene : Synthesis, Reactions and Uses. In: European Journal of Organic Chemistry. 2019.
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