Recent High Pressure Kinetics of the Reactions of Metal Complexes in Solution

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    1 Citation (Scopus)

    Abstract

    The first high pressure study on a fast inorganic reaction was reported by Brower in 1968. Since then, various high pressure apparatus for the study of fast reactions in solution, such as high-pressure T-jump, P-jump, NMR, stopped-flow, etc., have been exploited with the increasing interest in the high pressure chemistry of fast inorganic reactions. In this review, after brief explanations of the apparatus and classification, the relation of activation volumes and complex formation and solvent exchange mechanisms of metal ions classified by the Langford and Gray classification, which is assigned on the basis of kinetic data at ambient pressure, is explained. Recent studies relevant to high pressure kinetics are also covered.

    Original languageEnglish
    Pages (from-to)221-226
    Number of pages6
    JournalReview of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
    Volume9
    Issue number3
    DOIs
    Publication statusPublished - 1999 Jan 1

    Fingerprint

    Coordination Complexes
    Metal complexes
    Kinetics
    kinetics
    metals
    metal ions
    Metal ions
    activation
    chemistry
    Ion exchange
    Chemical activation
    nuclear magnetic resonance
    Nuclear magnetic resonance

    Keywords

    • activation volume
    • complex formation
    • fast reaction
    • high pressure apparatus
    • mechanism
    • solvent exchange

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

    Cite this

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    abstract = "The first high pressure study on a fast inorganic reaction was reported by Brower in 1968. Since then, various high pressure apparatus for the study of fast reactions in solution, such as high-pressure T-jump, P-jump, NMR, stopped-flow, etc., have been exploited with the increasing interest in the high pressure chemistry of fast inorganic reactions. In this review, after brief explanations of the apparatus and classification, the relation of activation volumes and complex formation and solvent exchange mechanisms of metal ions classified by the Langford and Gray classification, which is assigned on the basis of kinetic data at ambient pressure, is explained. Recent studies relevant to high pressure kinetics are also covered.",
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