Redox-active radical polymers for a totally organic rechargeable battery

Research output: Chapter in Book/Report/Conference proceedingConference contribution

12 Citations (Scopus)

Abstract

"Radical polymers" bearing a high density of unpaired electrons in a pendant, non-conjugated fashion on each repeating unit were utilized as cathode- and anode-active materials in a totally organic-based rechargeable battery. Careful molecular design of radical polymers such as nitroxide and galvinoxyl derivatives produced remarkably stable p- and n-type redox couples, which provided three different battery configurations. The power-rate performance of these cells was excellent (360 C rate, 10 sec charge/discharge), as a result of the rapid redox process of the organic radical moieties in the amorphous polymer layer. Organic polymer-based electrodes also allowed their utilization to a flexible, paper-like, and transparent rechargeable energy-storage device.

Original languageEnglish
Title of host publicationACS Symposium Series
PublisherAmerican Chemical Society
Pages45-53
Number of pages9
Volume1096
ISBN (Print)9780841226319
DOIs
Publication statusPublished - 2012

Publication series

NameACS Symposium Series
Volume1096
ISSN (Print)00976156
ISSN (Electronic)19475918

Fingerprint

Secondary batteries
Polymers
Bearings (structural)
Organic polymers
Energy storage
Anodes
Cathodes
Derivatives
Electrodes
Electrons
Oxidation-Reduction

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Suga, T., & Nishide, H. (2012). Redox-active radical polymers for a totally organic rechargeable battery. In ACS Symposium Series (Vol. 1096, pp. 45-53). (ACS Symposium Series; Vol. 1096). American Chemical Society. https://doi.org/10.1021/bk-2012-1096.ch003

Redox-active radical polymers for a totally organic rechargeable battery. / Suga, Takeo; Nishide, Hiroyuki.

ACS Symposium Series. Vol. 1096 American Chemical Society, 2012. p. 45-53 (ACS Symposium Series; Vol. 1096).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Suga, T & Nishide, H 2012, Redox-active radical polymers for a totally organic rechargeable battery. in ACS Symposium Series. vol. 1096, ACS Symposium Series, vol. 1096, American Chemical Society, pp. 45-53. https://doi.org/10.1021/bk-2012-1096.ch003
Suga T, Nishide H. Redox-active radical polymers for a totally organic rechargeable battery. In ACS Symposium Series. Vol. 1096. American Chemical Society. 2012. p. 45-53. (ACS Symposium Series). https://doi.org/10.1021/bk-2012-1096.ch003
Suga, Takeo ; Nishide, Hiroyuki. / Redox-active radical polymers for a totally organic rechargeable battery. ACS Symposium Series. Vol. 1096 American Chemical Society, 2012. pp. 45-53 (ACS Symposium Series).
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