Abstract
A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.
| Original language | English |
|---|---|
| Title of host publication | Polymer Preprints, Japan |
| Pages | 1388 |
| Number of pages | 1 |
| Volume | 54 |
| Edition | 1 |
| Publication status | Published - 2005 |
| Event | 54th SPSJ Annual Meeting 2005 - Yokohama Duration: 2005 May 25 → 2005 May 27 |
Other
| Other | 54th SPSJ Annual Meeting 2005 |
|---|---|
| City | Yokohama |
| Period | 05/5/25 → 05/5/27 |
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Keywords
- Cyclic voltammetry
- Dithioltihone
- Oxidative polymerization
- Polythiophene
- Redox active material
ASJC Scopus subject areas
- Engineering(all)
Cite this
Redox property of 3-dithiolthione-substituted polythiophene and its membrane. / Takemura, Ichiro; Utsunomiya, Saori; Takeoka, Shinji; Nishide, Hiroyuki.
Polymer Preprints, Japan. Vol. 54 1. ed. 2005. p. 1388.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Redox property of 3-dithiolthione-substituted polythiophene and its membrane
AU - Takemura, Ichiro
AU - Utsunomiya, Saori
AU - Takeoka, Shinji
AU - Nishide, Hiroyuki
PY - 2005
Y1 - 2005
N2 - A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.
AB - A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.
KW - Cyclic voltammetry
KW - Dithioltihone
KW - Oxidative polymerization
KW - Polythiophene
KW - Redox active material
UR - http://www.scopus.com/inward/record.url?scp=33645634968&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33645634968&partnerID=8YFLogxK
M3 - Conference contribution
VL - 54
SP - 1388
BT - Polymer Preprints, Japan
ER -