Redox property of 3-dithiolthione-substituted polythiophene and its membrane

Ichiro Takemura; Saori Utsunomiya; Shinji Takeoka; Hiroyuki Nishide

Redox property of 3-dithiolthione-substituted polythiophene and its membrane

Ichiro Takemura, Saori Utsunomiya, Shinji Takeoka, Hiroyuki Nishide

School of Advanced Science and Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.

Original language	English
Number of pages	1
Publication status	Published - 2005 Dec 1
Event	54th SPSJ Annual Meeting 2005 - Yokohama, Japan Duration: 2005 May 25 → 2005 May 27

Conference

Conference	54th SPSJ Annual Meeting 2005
Country	Japan
City	Yokohama
Period	05/5/25 → 05/5/27

Keywords

Cyclic voltammetry
Dithioltihone
Oxidative polymerization
Polythiophene
Redox active material

ASJC Scopus subject areas

Engineering(all)

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Cite this

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title = "Redox property of 3-dithiolthione-substituted polythiophene and its membrane",

abstract = "A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.",

keywords = "Cyclic voltammetry, Dithioltihone, Oxidative polymerization, Polythiophene, Redox active material",

author = "Ichiro Takemura and Saori Utsunomiya and Shinji Takeoka and Hiroyuki Nishide",

year = "2005",

month = dec,

day = "1",

language = "English",

note = "54th SPSJ Annual Meeting 2005 ; Conference date: 25-05-2005 Through 27-05-2005",

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TY - CONF

T1 - Redox property of 3-dithiolthione-substituted polythiophene and its membrane

AU - Takemura, Ichiro

AU - Utsunomiya, Saori

AU - Takeoka, Shinji

AU - Nishide, Hiroyuki

PY - 2005/12/1

Y1 - 2005/12/1

N2 - A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.

AB - A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.

KW - Cyclic voltammetry

KW - Dithioltihone

KW - Oxidative polymerization

KW - Polythiophene

KW - Redox active material

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M3 - Paper

AN - SCOPUS:33645634968

T2 - 54th SPSJ Annual Meeting 2005

Y2 - 25 May 2005 through 27 May 2005

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