Redox property of 3-dithiolthione-substituted polythiophene and its membrane

Ichiro Takemura, Saori Utsunomiya, Shinji Takeoka, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages1388
Number of pages1
Volume54
Edition1
Publication statusPublished - 2005
Event54th SPSJ Annual Meeting 2005 - Yokohama
Duration: 2005 May 252005 May 27

Other

Other54th SPSJ Annual Meeting 2005
CityYokohama
Period05/5/2505/5/27

Fingerprint

Bearings (structural)
Membranes
Cyclization
Thiophene
Polymers
Paramagnetic resonance
Esters
Positive ions
Polymerization
Spectroscopy
Derivatives
Oxidation
Electrodes
Acids
Oxidation-Reduction

Keywords

  • Cyclic voltammetry
  • Dithioltihone
  • Oxidative polymerization
  • Polythiophene
  • Redox active material

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Takemura, I., Utsunomiya, S., Takeoka, S., & Nishide, H. (2005). Redox property of 3-dithiolthione-substituted polythiophene and its membrane. In Polymer Preprints, Japan (1 ed., Vol. 54, pp. 1388)

Redox property of 3-dithiolthione-substituted polythiophene and its membrane. / Takemura, Ichiro; Utsunomiya, Saori; Takeoka, Shinji; Nishide, Hiroyuki.

Polymer Preprints, Japan. Vol. 54 1. ed. 2005. p. 1388.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Takemura, I, Utsunomiya, S, Takeoka, S & Nishide, H 2005, Redox property of 3-dithiolthione-substituted polythiophene and its membrane. in Polymer Preprints, Japan. 1 edn, vol. 54, pp. 1388, 54th SPSJ Annual Meeting 2005, Yokohama, 05/5/25.
Takemura I, Utsunomiya S, Takeoka S, Nishide H. Redox property of 3-dithiolthione-substituted polythiophene and its membrane. In Polymer Preprints, Japan. 1 ed. Vol. 54. 2005. p. 1388
Takemura, Ichiro ; Utsunomiya, Saori ; Takeoka, Shinji ; Nishide, Hiroyuki. / Redox property of 3-dithiolthione-substituted polythiophene and its membrane. Polymer Preprints, Japan. Vol. 54 1. ed. 2005. pp. 1388
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