Abstract
A polythiophene derivative bearing the pendant dithiolthione group was synthesized by oxidative polymerization of 3-thiophene malonic acid dimethyl ester and the following cyclization. UV-vis and ESR spectroscopy indicated that a radical cation was formed by oxidation of the dithiolthione ring. Membrane of the polymer was redox active and applicable to an electrode material.
| Original language | English |
|---|---|
| Title of host publication | Polymer Preprints, Japan |
| Pages | 1388 |
| Number of pages | 1 |
| Volume | 54 |
| Edition | 1 |
| Publication status | Published - 2005 |
| Event | 54th SPSJ Annual Meeting 2005 - Yokohama Duration: 2005 May 25 → 2005 May 27 |
Other
| Other | 54th SPSJ Annual Meeting 2005 |
|---|---|
| City | Yokohama |
| Period | 05/5/25 → 05/5/27 |
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Keywords
- Cyclic voltammetry
- Dithioltihone
- Oxidative polymerization
- Polythiophene
- Redox active material
ASJC Scopus subject areas
- Engineering(all)
Cite this
Takemura, I., Utsunomiya, S., Takeoka, S., & Nishide, H. (2005). Redox property of 3-dithiolthione-substituted polythiophene and its membrane. In Polymer Preprints, Japan (1 ed., Vol. 54, pp. 1388)