Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

Hiroaki Konishi, Takeo Suga, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages3980
Number of pages1
Volume55
Edition2
Publication statusPublished - 2006
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CityToyama
Period06/9/2006/9/22

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Keywords

  • Electrode-active material
  • Nitroxide radical
  • Photo-crosslinking
  • Polynorbornene
  • Secondary battery

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Konishi, H., Suga, T., & Nishide, H. (2006). Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s. In Polymer Preprints, Japan (2 ed., Vol. 55, pp. 3980)