Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

Hiroaki Konishi, Takeo Suga, Hiroyuki Nishide

Research output: Contribution to conferencePaper

Abstract

Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.

Original languageEnglish
Number of pages1
Publication statusPublished - 2006 Dec 1
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

Keywords

  • Electrode-active material
  • Nitroxide radical
  • Photo-crosslinking
  • Polynorbornene
  • Secondary battery

ASJC Scopus subject areas

  • Engineering(all)

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  • Cite this

    Konishi, H., Suga, T., & Nishide, H. (2006). Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s. Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.