Relaxation phenomenon in the formation of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3

Yasuhide Inoue, Hiroki Sato, Yasumasa Koyama

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    Abstract

    The formation of the C-type orbital-ordered (COO) state from the disordered cubic (DC) state in Sr1-xNdxMnO3 (SNMO) with the simple perovskite structure has been examined mainly by transmission electron microscopy. As the COO state has tetragonal I4/mcm symmetry, its formation is associated with the cubic-to-tetragonal structural transition. It was found that, when SNMO samples were cooled down from the DC state, the R25-type rotational displacement of MnO6 octahedra was first induced, together with the symmetry change into the tetragonal I4/mcm structure. The C-type orbital ordering then appeared due to the induction of the Jahn-Teller distortion as a response of a lattice system to this orbital ordering. Because no symmetry change occurred in the latter case, the Jahn-Teller distortion can be regarded as a dilatational distortion. One interesting feature is that the appearance of the dilatational Jahn-Teller distortion led to a nanometer-scale banded structure, characterized by an alternating array of two tetragonal variants with different c/a values. In addition, the formation of the COO state from the DC state exhibited a time-relaxation phenomenon. The origin of this relaxation phenomenon is also discussed here in terms of the competition between the tetragonal spontaneous strain for the rotational displacement and the dilatational Jahn-Teller distortion for orbital ordering.

    Original languageEnglish
    Article numbere024714
    JournalJournal of the Physical Society of Japan
    Volume85
    Issue number2
    DOIs
    Publication statusPublished - 2016 Feb 15

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    orbitals
    symmetry
    induction
    relaxation time
    transmission electron microscopy

    ASJC Scopus subject areas

    • Physics and Astronomy(all)

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    Relaxation phenomenon in the formation of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 . / Inoue, Yasuhide; Sato, Hiroki; Koyama, Yasumasa.

    In: Journal of the Physical Society of Japan, Vol. 85, No. 2, e024714, 15.02.2016.

    Research output: Contribution to journalArticle

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    abstract = "The formation of the C-type orbital-ordered (COO) state from the disordered cubic (DC) state in Sr1-xNdxMnO3 (SNMO) with the simple perovskite structure has been examined mainly by transmission electron microscopy. As the COO state has tetragonal I4/mcm symmetry, its formation is associated with the cubic-to-tetragonal structural transition. It was found that, when SNMO samples were cooled down from the DC state, the R25-type rotational displacement of MnO6 octahedra was first induced, together with the symmetry change into the tetragonal I4/mcm structure. The C-type orbital ordering then appeared due to the induction of the Jahn-Teller distortion as a response of a lattice system to this orbital ordering. Because no symmetry change occurred in the latter case, the Jahn-Teller distortion can be regarded as a dilatational distortion. One interesting feature is that the appearance of the dilatational Jahn-Teller distortion led to a nanometer-scale banded structure, characterized by an alternating array of two tetragonal variants with different c/a values. In addition, the formation of the COO state from the DC state exhibited a time-relaxation phenomenon. The origin of this relaxation phenomenon is also discussed here in terms of the competition between the tetragonal spontaneous strain for the rotational displacement and the dilatational Jahn-Teller distortion for orbital ordering.",
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    AU - Koyama, Yasumasa

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