Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment

Yusuke Ide, Nozomu Inami, Hideya Hattori, Kanji Saito, Minoru Sohmiya, Nao Tsunoji, Kenji Komaguchi, Tsuneji Sano, Yoshio Bando, Dmitri Golberg, Yoshiyuki Sugahara

    Research output: Contribution to journalArticle

    65 Citations (Scopus)

    Abstract

    Although tremendous effort has been directed to synthesizing advanced TiO2, it remains difficult to obtain TiO2 exhibiting a photocatalytic efficiency higher than that of P25, a benchmark photocatalyst. P25 is composed of anatase, rutile, and amorphous TiO2 particles, and photoexcited electron transfer and subsequent charge separation at the anatase-rutile particle interfaces explain its high photocatalytic efficiency. Herein, we report on a facile and rational hydrothermal treatment of P25 to selectively convert the amorphous component into crystalline TiO2, which is deposited between the original anatase and rutile particles to increase the particle interfaces and thus enhance charge separation. This process produces a new TiO2 exhibiting a considerably enhanced photocatalytic efficiency. This method of synthesizing this TiO2, inspired by a recently burgeoning zeolite design, promises to make TiO2 applications more feasible and effective. Connections matter: Hydrothermal treatment of P25 TiO2 selectively converts the amorphous component into crystalline TiO2, which is deposited between the original anatase and rutile component particles to increase the particle inter-faces, and thus considerably enhances charge separation and photocatalytic efficiency.

    Original languageEnglish
    Pages (from-to)3600-3605
    Number of pages6
    JournalAngewandte Chemie - International Edition
    Volume55
    Issue number11
    DOIs
    Publication statusPublished - 2016 Mar 7

    Fingerprint

    Titanium dioxide
    Nanoparticles
    Crystalline materials
    Photocatalysts
    Zeolites
    titanium dioxide
    Electrons

    Keywords

    • charge separation
    • dye-sensitized solar cell
    • photocatalysis
    • titanium dioxide
    • zeolite

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)

    Cite this

    Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment. / Ide, Yusuke; Inami, Nozomu; Hattori, Hideya; Saito, Kanji; Sohmiya, Minoru; Tsunoji, Nao; Komaguchi, Kenji; Sano, Tsuneji; Bando, Yoshio; Golberg, Dmitri; Sugahara, Yoshiyuki.

    In: Angewandte Chemie - International Edition, Vol. 55, No. 11, 07.03.2016, p. 3600-3605.

    Research output: Contribution to journalArticle

    Ide, Yusuke ; Inami, Nozomu ; Hattori, Hideya ; Saito, Kanji ; Sohmiya, Minoru ; Tsunoji, Nao ; Komaguchi, Kenji ; Sano, Tsuneji ; Bando, Yoshio ; Golberg, Dmitri ; Sugahara, Yoshiyuki. / Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment. In: Angewandte Chemie - International Edition. 2016 ; Vol. 55, No. 11. pp. 3600-3605.
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