Abstract
Kinetic and equilibrium constants of nitrogen coordination to cyclopentadienylmanganese (CpMn) are spectroscopically determined by using the membrane of the copolymer of (vinylmethylcyclopentadienyl)dicarbonylmanganese and octyl methacrylate. Nitrogen transport through the membrane is selectively augmented due to the rapid and reversible coordination of nitrogen to the fixed CpMn. The facilitated nitrogen-transport behavior is in accordance with a dual-mode transport model to give diffusion coefficients of the penetrant.
| Original language | English |
|---|---|
| Pages (from-to) | 7175-7179 |
| Number of pages | 5 |
| Journal | Journal of the American Chemical Society |
| Volume | 111 |
| Issue number | 18 |
| Publication status | Published - 1989 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Reversible coordination and facilitated transport of molecular nitrogen in poly((vinylcyclopentadienyl)manganese) membrane. / Nishide, Hiroyuki; Kawakami, Hiroyoshi; Kurimura, Yoshimi; Tsuchida, Eishun.
In: Journal of the American Chemical Society, Vol. 111, No. 18, 1989, p. 7175-7179.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Reversible coordination and facilitated transport of molecular nitrogen in poly((vinylcyclopentadienyl)manganese) membrane
AU - Nishide, Hiroyuki
AU - Kawakami, Hiroyoshi
AU - Kurimura, Yoshimi
AU - Tsuchida, Eishun
PY - 1989
Y1 - 1989
N2 - Kinetic and equilibrium constants of nitrogen coordination to cyclopentadienylmanganese (CpMn) are spectroscopically determined by using the membrane of the copolymer of (vinylmethylcyclopentadienyl)dicarbonylmanganese and octyl methacrylate. Nitrogen transport through the membrane is selectively augmented due to the rapid and reversible coordination of nitrogen to the fixed CpMn. The facilitated nitrogen-transport behavior is in accordance with a dual-mode transport model to give diffusion coefficients of the penetrant.
AB - Kinetic and equilibrium constants of nitrogen coordination to cyclopentadienylmanganese (CpMn) are spectroscopically determined by using the membrane of the copolymer of (vinylmethylcyclopentadienyl)dicarbonylmanganese and octyl methacrylate. Nitrogen transport through the membrane is selectively augmented due to the rapid and reversible coordination of nitrogen to the fixed CpMn. The facilitated nitrogen-transport behavior is in accordance with a dual-mode transport model to give diffusion coefficients of the penetrant.
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UR - http://www.scopus.com/inward/citedby.url?scp=0005161624&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0005161624
VL - 111
SP - 7175
EP - 7179
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 18
ER -