Abstract
The Rh-catalyzed hydroarylative and hydrovinylative cyclization of diynes with aryl ketones or enones gave monocyclic 1,3-dienes. Enynes also underwent the same reaction and chiral products were obtained with high ee using a chiral Rh catalyst. Carbonyl-directed activation of aromatic and vinylic C-H bonds is likely the initial step in the present transformation.
| Original language | English |
|---|---|
| Pages (from-to) | 3097-3099 |
| Number of pages | 3 |
| Journal | Organic Letters |
| Volume | 9 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2007 Aug 2 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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Tsuchikama, K., Kuwata, Y., Tahara, Y. K., Yoshinami, Y., & Shibata, T. (2007). Rh-catalyzed cyclization of diynes and enynes initiated by carbonyl-directed activation of aromatic and vinylic C-H bonds. Organic Letters, 9(16), 3097-3099. https://doi.org/10.1021/ol0711669