Rh-catalyzed intermolecular and enantioselective [4 + 2] cycloaddition of 1,3-dienes with dimethyl acetylenedicarboxylate

Takanori Shibata, Daisuke Fujiwara, Kohei Endo

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    Abstract

    A Rh-BINAP complex catalyzed an intermolecular and enantioselective [4 + 2] cycloaddition of 1-monosubstituted, 1,1- or 1,2-disubstituted buta-1,3-dienes with dimethyl acetylenedicarboxylate to give chiral cyclohexa-1,4-dienes.

    Original languageEnglish
    Pages (from-to)464-467
    Number of pages4
    JournalOrganic and Biomolecular Chemistry
    Volume6
    Issue number3
    DOIs
    Publication statusPublished - 2008

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    ASJC Scopus subject areas

    • Biochemistry, Genetics and Molecular Biology(all)
    • Chemistry(all)

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