Rh-catalyzed intermolecular and enantioselective [4 + 2] cycloaddition of 1,3-dienes with dimethyl acetylenedicarboxylate

Takanori Shibata, Daisuke Fujiwara, Kohei Endo

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A Rh-BINAP complex catalyzed an intermolecular and enantioselective [4 + 2] cycloaddition of 1-monosubstituted, 1,1- or 1,2-disubstituted buta-1,3-dienes with dimethyl acetylenedicarboxylate to give chiral cyclohexa-1,4-dienes.

Original languageEnglish
Pages (from-to)464-467
Number of pages4
JournalOrganic and Biomolecular Chemistry
Volume6
Issue number3
DOIs
Publication statusPublished - 2008 Feb 1

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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