Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands

Hiroki Kondo, Kenichiro Itami, Junichiro Yamaguchi

    Research output: Contribution to journalArticle

    13 Citations (Scopus)

    Abstract

    A Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes has been developed. Acyl aminocyclopropanes were reacted with hydrosilanes in the presence of Rh catalysts to afford ring-opened hydrosilylated adducts through carbon-carbon (C-C) bond cleavage of the cyclopropane ring. The regioselectivity of the addition of silanes (linear or branched) can be switched by changing the monophosphine ligand. This C-C bond cleavage/hydrosilylation methodology is applicable to the synthesis of silanediol precursors.

    Original languageEnglish
    Pages (from-to)3799-3803
    Number of pages5
    JournalChemical Science
    Volume8
    Issue number5
    DOIs
    Publication statusPublished - 2017

    ASJC Scopus subject areas

    • Chemistry(all)

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