Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

Takanori Shibata, Shunsuke Maekawa, Kohei Tamura

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

In the presence of a catalytic amount of RhCI(PPh3)3, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

Original languageEnglish
Pages (from-to)1261-1270
Number of pages10
JournalHeterocycles
Volume76
Issue number2
DOIs
Publication statusPublished - 2008 Nov 1

Keywords

  • Bond Cleavage
  • Cycloaddition
  • Cyclopentadiene
  • Cyclopropene
  • Rhodium

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage'. Together they form a unique fingerprint.

  • Cite this