Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

Takanori Shibata, Shunsuke Maekawa, Kohei Tamura

    Research output: Contribution to journalArticle

    15 Citations (Scopus)

    Abstract

    In the presence of a catalytic amount of RhCI(PPh3)3, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

    Original languageEnglish
    Pages (from-to)1261-1270
    Number of pages10
    JournalHeterocycles
    Volume76
    Issue number2
    DOIs
    Publication statusPublished - 2008 Nov 1

    Fingerprint

    Rhodium
    Cycloaddition
    Cycloaddition Reaction
    Carbon
    Cyclopentanes
    Derivatives
    cyclopropene

    Keywords

    • Bond Cleavage
    • Cycloaddition
    • Cyclopentadiene
    • Cyclopropene
    • Rhodium

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Organic Chemistry
    • Pharmacology

    Cite this

    Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage. / Shibata, Takanori; Maekawa, Shunsuke; Tamura, Kohei.

    In: Heterocycles, Vol. 76, No. 2, 01.11.2008, p. 1261-1270.

    Research output: Contribution to journalArticle

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