Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes

Takanori Shibata, Yuri Takesue, Sho Kadowaki, Kentaro Takagi

Research output: Contribution to journalArticlepeer-review

66 Citations (Scopus)

Abstract

Wilkinson's catalyst [RhCl(PPh3)3] catalyzed a cycloisomerization of allenynes which possess geminal methyls on the allene terminus and an intramolecular ene-type reaction proceeded to give various cross-conjugated trienes. Thermal Diels-Alder reaction of the obtained triene was examined to give a bicyclic compound in a high yield.

Original languageEnglish
Pages (from-to)268-270
Number of pages3
JournalSynlett
Issue number2
DOIs
Publication statusPublished - 2003 Jan 1
Externally publishedYes

Keywords

  • Alkynes
  • Allenes
  • Catalysis
  • Ene reactions
  • Rhodium

ASJC Scopus subject areas

  • Organic Chemistry

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