Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

Maiko Otsuka, Hiroya Yokoyama, Kohei Endo, Takanori Shibata

    Research output: Contribution to journalArticle

    13 Citations (Scopus)

    Abstract

    A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.

    Original languageEnglish
    Pages (from-to)3815-3818
    Number of pages4
    JournalOrganic and Biomolecular Chemistry
    Volume10
    Issue number19
    DOIs
    Publication statusPublished - 2012 May 21

    Fingerprint

    Styrenes
    styrenes
    Amines
    amines
    Ligands
    ligands
    vinyltoluene

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Organic Chemistry
    • Biochemistry

    Cite this

    Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange. / Otsuka, Maiko; Yokoyama, Hiroya; Endo, Kohei; Shibata, Takanori.

    In: Organic and Biomolecular Chemistry, Vol. 10, No. 19, 21.05.2012, p. 3815-3818.

    Research output: Contribution to journalArticle

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