Scanning Tunneling Microscopy of Platinum Deposits on the Basal Plane of Highly Oriented Pyrolytic Graphite

Steve Eppell, Gary S. Chottiner, Daniel Alberto Scherson, Gary Pruett

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Scanning tunneling microscopy images of Pt vapor deposited on the basal plane of highly oriented pyrolytic graphite, HOPG(bp), under ultrahigh vacuum have been recorded in air at room temperature. Areas of specimens masked during Pt deposition displayed characteristic corrugations associated with bare graphite over 20˟ 20 nm2 areas, with no indication of surface damage or contamination over much larger sections, 400 ˟ 400 nm2. Unmasked areas of samples with coverages in the range between ca. 10‥ and 40‥, as estimated from X-ray photoelectron spectroscopy, contained small features (5-nm average lateral dimension) with internal structures of atomic dimensions. An analysis of variance of the maximum heights for clusters observed on representative areas of 10 ‥, 28 ‥, and 40 ‥ Pt/ HOPG(bp) specimens provided evidence that the means (ca. 0.38 nm) are not significantly different (P = 0.80). Hence, the three distributions appear to have been drawn from the same parent distribution. This strongly suggests that deposition of Pt on HOPG(bp) under the experimental conditions employed in this work gives rise to the preferential formation of essentially two-dimensional Pt structures on the surface.

Original languageEnglish
Pages (from-to)1316-1319
Number of pages4
JournalLangmuir
Volume6
Issue number7
DOIs
Publication statusPublished - 1990 Jan 1
Externally publishedYes

Fingerprint

Graphite
pyrolytic graphite
Scanning tunneling microscopy
Platinum
scanning tunneling microscopy
platinum
Deposits
deposits
Ultrahigh vacuum
Analysis of variance (ANOVA)
Contamination
X ray photoelectron spectroscopy
Vapors
analysis of variance
Air
ultrahigh vacuum
indication
contamination
graphite
photoelectron spectroscopy

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Scanning Tunneling Microscopy of Platinum Deposits on the Basal Plane of Highly Oriented Pyrolytic Graphite. / Eppell, Steve; Chottiner, Gary S.; Scherson, Daniel Alberto; Pruett, Gary.

In: Langmuir, Vol. 6, No. 7, 01.01.1990, p. 1316-1319.

Research output: Contribution to journalArticle

Eppell, Steve ; Chottiner, Gary S. ; Scherson, Daniel Alberto ; Pruett, Gary. / Scanning Tunneling Microscopy of Platinum Deposits on the Basal Plane of Highly Oriented Pyrolytic Graphite. In: Langmuir. 1990 ; Vol. 6, No. 7. pp. 1316-1319.
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abstract = "Scanning tunneling microscopy images of Pt vapor deposited on the basal plane of highly oriented pyrolytic graphite, HOPG(bp), under ultrahigh vacuum have been recorded in air at room temperature. Areas of specimens masked during Pt deposition displayed characteristic corrugations associated with bare graphite over 20˟ 20 nm2 areas, with no indication of surface damage or contamination over much larger sections, 400 ˟ 400 nm2. Unmasked areas of samples with coverages in the range between ca. 10‥ and 40‥, as estimated from X-ray photoelectron spectroscopy, contained small features (5-nm average lateral dimension) with internal structures of atomic dimensions. An analysis of variance of the maximum heights for clusters observed on representative areas of 10 ‥, 28 ‥, and 40 ‥ Pt/ HOPG(bp) specimens provided evidence that the means (ca. 0.38 nm) are not significantly different (P = 0.80). Hence, the three distributions appear to have been drawn from the same parent distribution. This strongly suggests that deposition of Pt on HOPG(bp) under the experimental conditions employed in this work gives rise to the preferential formation of essentially two-dimensional Pt structures on the surface.",
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