Self-assembly of porphyrins with uracil and melamine derivatives

Satoshi Arai, Daisuke Niwa, Shinji Takeoka, Hiroyuki Nishide

Research output: Contribution to conference › Paper

Abstract

Porphyrin derivatives UP1 was synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative. Meso-UP was synthesized, and then atrop isomere (αα, αβ) were separated stably by column chromatography. The mixed benzene solution with Glu-M and UP1 was gelated at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, which means well-defined porphyrin structure. When Glu-M was added to suspended Meso-UPαα CHCl3 solution, the clear solution was obtained, which means formation of hydrogen bonded assembly.

Original languageEnglish
Pages4913-4914
Number of pages2
Publication statusPublished - 2005 Dec 1
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: 2005 Sep 20 → 2005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period05/9/20 → 05/9/22

Keywords

  • Atrop isomer
  • Hydrogen bond
  • Porphyrin
  • Self-assembly

ASJC Scopus subject areas

  • Engineering(all)

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    Arai, S., Niwa, D., Takeoka, S., & Nishide, H. (2005). Self-assembly of porphyrins with uracil and melamine derivatives. 4913-4914. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.