Abstract
Porphyrin derivatives UP1 was synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative. Meso-UP was synthesized, and then atrop isomere (αα, αβ) were separated stably by column chromatography. The mixed benzene solution with Glu-M and UP1 was gelated at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, which means well-defined porphyrin structure. When Glu-M was added to suspended Meso-UPαα CHCl3 solution, the clear solution was obtained, which means formation of hydrogen bonded assembly.
Original language | English |
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Pages | 4913-4914 |
Number of pages | 2 |
Publication status | Published - 2005 Dec 1 |
Event | 54th SPSJ Symposium on Macromolecules - Yamagata, Japan Duration: 2005 Sep 20 → 2005 Sep 22 |
Other
Other | 54th SPSJ Symposium on Macromolecules |
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Country | Japan |
City | Yamagata |
Period | 05/9/20 → 05/9/22 |
Keywords
- Atrop isomer
- Hydrogen bond
- Porphyrin
- Self-assembly
ASJC Scopus subject areas
- Engineering(all)