Abstract
Porphyrin derivatives UP1 was synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative. Meso-UP was synthesized, and then atrop isomere (αα, αβ) were separated stably by column chromatography. The mixed benzene solution with Glu-M and UP1 was gelated at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, which means well-defined porphyrin structure. When Glu-M was added to suspended Meso-UPαα CHCl3 solution, the clear solution was obtained, which means formation of hydrogen bonded assembly.
| Original language | English |
|---|---|
| Title of host publication | Polymer Preprints, Japan |
| Pages | 4913-4914 |
| Number of pages | 2 |
| Volume | 54 |
| Edition | 2 |
| Publication status | Published - 2005 |
| Event | 54th SPSJ Symposium on Macromolecules - Yamagata Duration: 2005 Sep 20 → 2005 Sep 22 |
Other
| Other | 54th SPSJ Symposium on Macromolecules |
|---|---|
| City | Yamagata |
| Period | 05/9/20 → 05/9/22 |
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Keywords
- Atrop isomer
- Hydrogen bond
- Porphyrin
- Self-assembly
ASJC Scopus subject areas
- Engineering(all)
Cite this
Self-assembly of porphyrins with uracil and melamine derivatives. / Arai, Satoshi; Niwa, Daisuke; Takeoka, Shinji; Nishide, Hiroyuki.
Polymer Preprints, Japan. Vol. 54 2. ed. 2005. p. 4913-4914.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Self-assembly of porphyrins with uracil and melamine derivatives
AU - Arai, Satoshi
AU - Niwa, Daisuke
AU - Takeoka, Shinji
AU - Nishide, Hiroyuki
PY - 2005
Y1 - 2005
N2 - Porphyrin derivatives UP1 was synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative. Meso-UP was synthesized, and then atrop isomere (αα, αβ) were separated stably by column chromatography. The mixed benzene solution with Glu-M and UP1 was gelated at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, which means well-defined porphyrin structure. When Glu-M was added to suspended Meso-UPαα CHCl3 solution, the clear solution was obtained, which means formation of hydrogen bonded assembly.
AB - Porphyrin derivatives UP1 was synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative. Meso-UP was synthesized, and then atrop isomere (αα, αβ) were separated stably by column chromatography. The mixed benzene solution with Glu-M and UP1 was gelated at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, which means well-defined porphyrin structure. When Glu-M was added to suspended Meso-UPαα CHCl3 solution, the clear solution was obtained, which means formation of hydrogen bonded assembly.
KW - Atrop isomer
KW - Hydrogen bond
KW - Porphyrin
KW - Self-assembly
UR - http://www.scopus.com/inward/record.url?scp=33645571001&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33645571001&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:33645571001
VL - 54
SP - 4913
EP - 4914
BT - Polymer Preprints, Japan
ER -