Self-oscillating soluble-insoluble changes of a polymer chain including an oxidizing agent induced by the Belousov-Zhabotinsky reaction

Yusuke Hara, Takamasa Sakai, Shingo Maeda, Shuji Hashimoto, Ryo Yoshida

    Research output: Contribution to journalArticle

    48 Citations (Scopus)


    A new type of self-oscillating polymer was prepared by utilizing the Belousov-Zhabotinsky reaction. In this study, capture sites with a positive charge for an oxidizing agent as a counterion were incorporated into the copolymer of N-isopropylacrylamide and the ruthenium complex as a catalyst. Soluble-insoluble self-oscillation of the polymer was first achieved without adding an oxidizing agent. The effect of temperature on the self-oscillating behavior was investigated. It was clarified that the polymer had two advantageous characteristics because of the higher LCST; one is to enable self-oscillation around body temperature, and the other is to cause the oscillation for a longer time without intermolecular aggregation among the polymer chains in the reduced state. This achievement of self-oscillation of polymer chains including an oxidizing agent may lead to their practical use under oxidant-free conditions.

    Original languageEnglish
    Pages (from-to)23316-23319
    Number of pages4
    JournalJournal of Physical Chemistry B
    Issue number49
    Publication statusPublished - 2005 Dec 15


    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry

    Cite this