Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance

Isao Hasegawa; Sumio Sakka; Yoshiyuki Sugahara; Kazuyuki Kuroda; Chuzo Kato

doi:10.1039/C39890000208

Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by ²⁹Si nuclear magnetic resonance

Isao Hasegawa, Sumio Sakka, Yoshiyuki Sugahara, Kazuyuki Kuroda, Chuzo Kato

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

The Si₈O₂₀^8- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO ₄^4- silicate anion or at the expense of Si ₆O₁₅^6- and highly cross-linked polymeric silicate anions which are once formed.

Original language	English
Pages (from-to)	208-210
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39890000208
Publication status	Published - 1989 Jan 1

ASJC Scopus subject areas

Molecular Medicine

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title = "Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance",

abstract = "The Si8O208- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 44- silicate anion or at the expense of Si 6O156- and highly cross-linked polymeric silicate anions which are once formed.",

author = "Isao Hasegawa and Sumio Sakka and Yoshiyuki Sugahara and Kazuyuki Kuroda and Chuzo Kato",

year = "1989",

month = jan,

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doi = "10.1039/C39890000208",

language = "English",

pages = "208--210",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance

AU - Hasegawa, Isao

AU - Sakka, Sumio

AU - Sugahara, Yoshiyuki

AU - Kuroda, Kazuyuki

AU - Kato, Chuzo

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The Si8O208- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 44- silicate anion or at the expense of Si 6O156- and highly cross-linked polymeric silicate anions which are once formed.

AB - The Si8O208- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 44- silicate anion or at the expense of Si 6O156- and highly cross-linked polymeric silicate anions which are once formed.

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