Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance

Isao Hasegawa, Sumio Sakka, Yoshiyuki Sugahara, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    53 Citations (Scopus)

    Abstract

    The Si8O20 8- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 4 4- silicate anion or at the expense of Si 6O15 6- and highly cross-linked polymeric silicate anions which are once formed.

    Original languageEnglish
    Pages (from-to)208-210
    Number of pages3
    JournalJournal of the Chemical Society, Chemical Communications
    Issue number4
    DOIs
    Publication statusPublished - 1989

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    Silicates
    Anions
    Magnetic Resonance Spectroscopy
    Negative ions
    Nuclear magnetic resonance
    tetramethylammonium

    ASJC Scopus subject areas

    • Molecular Medicine

    Cite this

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    title = "Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance",
    abstract = "The Si8O20 8- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 4 4- silicate anion or at the expense of Si 6O15 6- and highly cross-linked polymeric silicate anions which are once formed.",
    author = "Isao Hasegawa and Sumio Sakka and Yoshiyuki Sugahara and Kazuyuki Kuroda and Chuzo Kato",
    year = "1989",
    doi = "10.1039/C39890000208",
    language = "English",
    pages = "208--210",
    journal = "Chemical Communications",
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    publisher = "Royal Society of Chemistry",
    number = "4",

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    TY - JOUR

    T1 - Silicate anions formed in tetramethylammonium silicate methanolic solutions as studied by 29Si nuclear magnetic resonance

    AU - Hasegawa, Isao

    AU - Sakka, Sumio

    AU - Sugahara, Yoshiyuki

    AU - Kuroda, Kazuyuki

    AU - Kato, Chuzo

    PY - 1989

    Y1 - 1989

    N2 - The Si8O20 8- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 4 4- silicate anion or at the expense of Si 6O15 6- and highly cross-linked polymeric silicate anions which are once formed.

    AB - The Si8O20 8- silicate anion is selectively formed in tetramethylammonium silicate methanolic solution from the SiO 4 4- silicate anion or at the expense of Si 6O15 6- and highly cross-linked polymeric silicate anions which are once formed.

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    U2 - 10.1039/C39890000208

    DO - 10.1039/C39890000208

    M3 - Article

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    EP - 210

    JO - Chemical Communications

    JF - Chemical Communications

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