Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

Satoshi Tsuneda; Kyoichi Saito; Shintaro Furusaki; Takanobu Sugo; Keizo Makuuchi

doi:10.1021/ie00019a600

Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

Satoshi Tsuneda, Kyoichi Saito^*, Shintaro Furusaki, Takanobu Sugo, Keizo Makuuchi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The sulfonic acid (SO₃H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO₃H density of 2.5 mol/kg of the H-type product.

Original language	English
Pages (from-to)	1464-1470
Number of pages	7
Journal	Industrial and Engineering Chemistry Research
Volume	32
Issue number	7
DOIs	https://doi.org/10.1021/ie00019a600
Publication status	Published - 1993 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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title = "Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers",

abstract = "The sulfonic acid (SO3H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO3H density of 2.5 mol/kg of the H-type product.",

author = "Satoshi Tsuneda and Kyoichi Saito and Shintaro Furusaki and Takanobu Sugo and Keizo Makuuchi",

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T1 - Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

AU - Tsuneda, Satoshi

AU - Saito, Kyoichi

AU - Furusaki, Shintaro

AU - Sugo, Takanobu

AU - Makuuchi, Keizo

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The sulfonic acid (SO3H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO3H density of 2.5 mol/kg of the H-type product.

AB - The sulfonic acid (SO3H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO3H density of 2.5 mol/kg of the H-type product.

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Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

Abstract

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