Simple introduction to sulfonic acid group onto polyethylene by radiation-induced cografting of sodium styrenesulfonate with hydrophilic monomers

Satoshi Tsuneda, Kyoichi Saito, Shintaro Furusaki, Takanobu Sugo, Keizo Makuuchi

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The sulfonic acid (SO3H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO3H density of 2.5 mol/kg of the H-type product.

Original languageEnglish
Pages (from-to)1464-1470
Number of pages7
JournalIndustrial and Engineering Chemistry Research
Volume32
Issue number7
Publication statusPublished - 1993 Jul
Externally publishedYes

Fingerprint

Sulfonic Acids
Polyethylene
Polyethylenes
Monomers
Sodium
sodium
Radiation
Acids
acid
membrane
Membranes
Acrylics
Electron beams
electron
radiation
hydroxyethyl methacrylate

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Environmental Science(all)
  • Polymers and Plastics

Cite this

Simple introduction to sulfonic acid group onto polyethylene by radiation-induced cografting of sodium styrenesulfonate with hydrophilic monomers. / Tsuneda, Satoshi; Saito, Kyoichi; Furusaki, Shintaro; Sugo, Takanobu; Makuuchi, Keizo.

In: Industrial and Engineering Chemistry Research, Vol. 32, No. 7, 07.1993, p. 1464-1470.

Research output: Contribution to journalArticle

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