SolGel-derived bridged polysilsesquioxane as a hydrogen peroxide decomposition catalyst: Immobilization of a dimanganese complex and its improved thermal stability

Hitomi Saito; Akira Ishisone; Yuhei Horikawa; Takeshi Ishiyama; Hideyuki Higashimura; Yoshiyuki Sugahara

doi:10.1246/cl.2012.591

SolGel-derived bridged polysilsesquioxane as a hydrogen peroxide decomposition catalyst: Immobilization of a dimanganese complex and its improved thermal stability

Hitomi Saito, Akira Ishisone, Yuhei Horikawa, Takeshi Ishiyama, Hideyuki Higashimura^*, Yoshiyuki Sugahara

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Bridged polysilsesquioxane possessing dimanganese complex moiety, a model complex for catalase, exhibited catalytic activity for the hydrogen peroxide decomposition reaction without any deactivation. The catalytic activity was mostly retained, even after 24-h acid treatment at 80 °C, improving thermal stability after immobilization.

Original language	English
Pages (from-to)	591-592
Number of pages	2
Journal	Chemistry Letters
Volume	41
Issue number	6
DOIs	https://doi.org/10.1246/cl.2012.591
Publication status	Published - 2012 Jun 6

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10.1246/cl.2012.591

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SolGel-derived bridged polysilsesquioxane as a hydrogen peroxide decomposition catalyst : Immobilization of a dimanganese complex and its improved thermal stability. / Saito, Hitomi; Ishisone, Akira; Horikawa, Yuhei; Ishiyama, Takeshi; Higashimura, Hideyuki; Sugahara, Yoshiyuki.

In: Chemistry Letters, Vol. 41, No. 6, 06.06.2012, p. 591-592.

Research output: Contribution to journal › Article › peer-review

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abstract = "Bridged polysilsesquioxane possessing dimanganese complex moiety, a model complex for catalase, exhibited catalytic activity for the hydrogen peroxide decomposition reaction without any deactivation. The catalytic activity was mostly retained, even after 24-h acid treatment at 80 °C, improving thermal stability after immobilization.",

author = "Hitomi Saito and Akira Ishisone and Yuhei Horikawa and Takeshi Ishiyama and Hideyuki Higashimura and Yoshiyuki Sugahara",

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T2 - Immobilization of a dimanganese complex and its improved thermal stability

AU - Saito, Hitomi

AU - Ishisone, Akira

AU - Horikawa, Yuhei

AU - Ishiyama, Takeshi

AU - Higashimura, Hideyuki

AU - Sugahara, Yoshiyuki

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AB - Bridged polysilsesquioxane possessing dimanganese complex moiety, a model complex for catalase, exhibited catalytic activity for the hydrogen peroxide decomposition reaction without any deactivation. The catalytic activity was mostly retained, even after 24-h acid treatment at 80 °C, improving thermal stability after immobilization.

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SolGel-derived bridged polysilsesquioxane as a hydrogen peroxide decomposition catalyst: Immobilization of a dimanganese complex and its improved thermal stability

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