Abstract
Intercalation of two diimines, 4,4′-bipyridine (4BPY) and 1,2-di(4-pyridine)ethylene (DPE), into the interlayer spaces of cobalt(II)-, nickel(II)- and copper(II)-montmorillonites by solid-solid reactions was investigated. The successful intercalation of these compounds through coordination to the interlayer exchangeable cations was confirmed by powder X-ray diffraction, infrared spectroscopy, elemental (CHN) analysis, and thermal analysis of the products. The presented solid-state intercalation of bidentate bridging ligands and in situ complex formation in the interlayer spaces of montmorillonite is a feasible way to prepare clay-coordination polymer-intercalation compounds, which cannot be obtained in conventional ion exchange reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 69-76 |
| Number of pages | 8 |
| Journal | Applied Clay Science |
| Volume | 19 |
| Issue number | 1-6 |
| DOIs | |
| Publication status | Published - 2001 Jul |
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Keywords
- 1,2-Di(4-pyridine)ethylene
- 4,4+′-Bipyridine
- Coordination polymer
- Intercalation
- Montmorillonite
- Solid-solid reaction
ASJC Scopus subject areas
- Geochemistry and Petrology
- Geology
Cite this
Solid-state intercalation of 4,4′-bipyridine and 1,2-di(4-pyridine) ethylene into the interlayer spaces of Co(II)-, Ni(II)- and Cu(II)-montmorillonites. / Khaorapapong, Nithima; Kuroda, Kazuyuki; Hashizume, Hideo; Ogawa, Makoto.
In: Applied Clay Science, Vol. 19, No. 1-6, 07.2001, p. 69-76.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solid-state intercalation of 4,4′-bipyridine and 1,2-di(4-pyridine) ethylene into the interlayer spaces of Co(II)-, Ni(II)- and Cu(II)-montmorillonites
AU - Khaorapapong, Nithima
AU - Kuroda, Kazuyuki
AU - Hashizume, Hideo
AU - Ogawa, Makoto
PY - 2001/7
Y1 - 2001/7
N2 - Intercalation of two diimines, 4,4′-bipyridine (4BPY) and 1,2-di(4-pyridine)ethylene (DPE), into the interlayer spaces of cobalt(II)-, nickel(II)- and copper(II)-montmorillonites by solid-solid reactions was investigated. The successful intercalation of these compounds through coordination to the interlayer exchangeable cations was confirmed by powder X-ray diffraction, infrared spectroscopy, elemental (CHN) analysis, and thermal analysis of the products. The presented solid-state intercalation of bidentate bridging ligands and in situ complex formation in the interlayer spaces of montmorillonite is a feasible way to prepare clay-coordination polymer-intercalation compounds, which cannot be obtained in conventional ion exchange reactions.
AB - Intercalation of two diimines, 4,4′-bipyridine (4BPY) and 1,2-di(4-pyridine)ethylene (DPE), into the interlayer spaces of cobalt(II)-, nickel(II)- and copper(II)-montmorillonites by solid-solid reactions was investigated. The successful intercalation of these compounds through coordination to the interlayer exchangeable cations was confirmed by powder X-ray diffraction, infrared spectroscopy, elemental (CHN) analysis, and thermal analysis of the products. The presented solid-state intercalation of bidentate bridging ligands and in situ complex formation in the interlayer spaces of montmorillonite is a feasible way to prepare clay-coordination polymer-intercalation compounds, which cannot be obtained in conventional ion exchange reactions.
KW - 1,2-Di(4-pyridine)ethylene
KW - 4,4+′-Bipyridine
KW - Coordination polymer
KW - Intercalation
KW - Montmorillonite
KW - Solid-solid reaction
UR - http://www.scopus.com/inward/record.url?scp=0035391161&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035391161&partnerID=8YFLogxK
U2 - 10.1016/S0169-1317(01)00055-2
DO - 10.1016/S0169-1317(01)00055-2
M3 - Article
AN - SCOPUS:0035391161
VL - 19
SP - 69
EP - 76
JO - Applied Clay Science
JF - Applied Clay Science
SN - 0169-1317
IS - 1-6
ER -