Solid-state intercalation of acrylamide into smectites and Na-taeniolite

Makoto Ogawa, Yasuyuki Nagafusa, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    45 Citations (Scopus)

    Abstract

    Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.

    Original languageEnglish
    Pages (from-to)291-302
    Number of pages12
    JournalApplied Clay Science
    Volume7
    Issue number4
    DOIs
    Publication statusPublished - 1992

    Fingerprint

    Acrylamide
    Intercalation
    smectite
    Intercalation compounds
    Ethylene Glycol
    Clay minerals
    Charge density
    mica
    ethylene
    Minerals
    clay mineral
    taeniolite
    Smectite
    solid state
    mineral
    temperature
    Temperature

    ASJC Scopus subject areas

    • Geochemistry and Petrology
    • Geology

    Cite this

    Solid-state intercalation of acrylamide into smectites and Na-taeniolite. / Ogawa, Makoto; Nagafusa, Yasuyuki; Kuroda, Kazuyuki; Kato, Chuzo.

    In: Applied Clay Science, Vol. 7, No. 4, 1992, p. 291-302.

    Research output: Contribution to journalArticle

    Ogawa, Makoto ; Nagafusa, Yasuyuki ; Kuroda, Kazuyuki ; Kato, Chuzo. / Solid-state intercalation of acrylamide into smectites and Na-taeniolite. In: Applied Clay Science. 1992 ; Vol. 7, No. 4. pp. 291-302.
    @article{3dba607b13c7403399a252be87ef2fd0,
    title = "Solid-state intercalation of acrylamide into smectites and Na-taeniolite",
    abstract = "Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.",
    author = "Makoto Ogawa and Yasuyuki Nagafusa and Kazuyuki Kuroda and Chuzo Kato",
    year = "1992",
    doi = "10.1016/0169-1317(92)90016-G",
    language = "English",
    volume = "7",
    pages = "291--302",
    journal = "Applied Clay Science",
    issn = "0169-1317",
    publisher = "Elsevier BV",
    number = "4",

    }

    TY - JOUR

    T1 - Solid-state intercalation of acrylamide into smectites and Na-taeniolite

    AU - Ogawa, Makoto

    AU - Nagafusa, Yasuyuki

    AU - Kuroda, Kazuyuki

    AU - Kato, Chuzo

    PY - 1992

    Y1 - 1992

    N2 - Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.

    AB - Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.

    UR - http://www.scopus.com/inward/record.url?scp=0027007629&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0027007629&partnerID=8YFLogxK

    U2 - 10.1016/0169-1317(92)90016-G

    DO - 10.1016/0169-1317(92)90016-G

    M3 - Article

    VL - 7

    SP - 291

    EP - 302

    JO - Applied Clay Science

    JF - Applied Clay Science

    SN - 0169-1317

    IS - 4

    ER -