Solid-state intercalation of acrylamide into smectites and Na-taeniolite

Makoto Ogawa, Yasuyuki Nagafusa, Kazuyuki Kuroda, Chuzo Kato

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.

Original languageEnglish
Pages (from-to)291-302
Number of pages12
JournalApplied Clay Science
Volume7
Issue number4
DOIs
Publication statusPublished - 1992 Nov

ASJC Scopus subject areas

  • Geology
  • Geochemistry and Petrology

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