Solution conductivity as a key factor for thin silica coating on colloidal silver

Ken Ichi Nomura, Shinji Fujii, Yoshimichi Ohki, Koichi Awazu, Makoto Fujimaki, Nobuko Fukuda, Tsutomu Hirakawa

    Research output: Contribution to journalArticle

    Abstract

    In order to utilize silver nanoparticles for various applications such as photocatalysts while maintaining their chemical stability, enhanced electric fields on the nanoparticle surfaces induced by localized surface plasmon excitation must be used effectively. For satisfying these requirements, an ultrathin silica coating with a thickness of only a few nm was formed around silver nanoparticles by a chemical reaction in a solution, while parameters such as the amount of sodium silicate and the number of dialysis procedures performed were changed. As a result, it was found that a key factor for obtaining stable thin-silica-coated silver nanoparticles is the conductivity of the solution. Using a solution with an appropriate conductivity above 2.7 mS/m, silica films can be coated on silver nanoparticles without causing deterioration of the plasmonic activity resulting from the aggregation of silver.

    Original languageEnglish
    JournalJapanese Journal of Applied Physics
    Volume48
    Issue number6 PART 2
    DOIs
    Publication statusPublished - 2009 Jun

    Fingerprint

    Silver
    silver
    Silica
    Nanoparticles
    silicon dioxide
    coatings
    Coatings
    conductivity
    nanoparticles
    sodium silicates
    dialysis
    Dialysis
    Chemical stability
    Photocatalysts
    deterioration
    Silicates
    Deterioration
    Chemical reactions
    chemical reactions
    Agglomeration

    ASJC Scopus subject areas

    • Engineering(all)
    • Physics and Astronomy(all)

    Cite this

    Solution conductivity as a key factor for thin silica coating on colloidal silver. / Nomura, Ken Ichi; Fujii, Shinji; Ohki, Yoshimichi; Awazu, Koichi; Fujimaki, Makoto; Fukuda, Nobuko; Hirakawa, Tsutomu.

    In: Japanese Journal of Applied Physics, Vol. 48, No. 6 PART 2, 06.2009.

    Research output: Contribution to journalArticle

    Nomura, Ken Ichi ; Fujii, Shinji ; Ohki, Yoshimichi ; Awazu, Koichi ; Fujimaki, Makoto ; Fukuda, Nobuko ; Hirakawa, Tsutomu. / Solution conductivity as a key factor for thin silica coating on colloidal silver. In: Japanese Journal of Applied Physics. 2009 ; Vol. 48, No. 6 PART 2.
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    AU - Fujii, Shinji

    AU - Ohki, Yoshimichi

    AU - Awazu, Koichi

    AU - Fujimaki, Makoto

    AU - Fukuda, Nobuko

    AU - Hirakawa, Tsutomu

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