Spontaneous Crack Healing in Nanostructured Silica-Based Thin Films

Shun Itoh, Satoshi Kodama, Maho Kobayashi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    Self-healing materials that can spontaneously repair damage under mild conditions are desirable in many applications. Significant progress has recently been made in the design of polymer materials capable of healing cracks at the molecular scale using reversible bonds; however, such a self-healing mechanism has rarely been applied to rigid inorganic materials. Here, we demonstrate the self-healing ability of lamellar silica-based thin films formed by self-assembly of silica precursors and quaternary ammonium-type surfactants. Specifically, spontaneous healing of cracks (typically less than 1.5 μm in width) was achieved under humid conditions even at room temperature. The randomly oriented lamellar structure with thin silica layers is suggested to play an essential role in crack closure and the reformation of siloxane networks on the fracture surface. These findings will lead to the creation of smart self-healing silica-based materials based on reversible siloxane bonds.

    Original languageEnglish
    Pages (from-to)10289-10294
    Number of pages6
    JournalACS Nano
    Volume11
    Issue number10
    DOIs
    Publication statusPublished - 2017 Oct 24

    Fingerprint

    healing
    Silicon Dioxide
    cracks
    Silica
    Siloxanes
    silicon dioxide
    Cracks
    Thin films
    thin films
    Self-healing materials
    siloxanes
    Crack closure
    Lamellar structures
    Ammonium Compounds
    Surface-Active Agents
    crack closure
    Self assembly
    Polymers
    Surface active agents
    Repair

    Keywords

    • mesostructures
    • self-assembly
    • self-healing
    • siloxane
    • thin films

    ASJC Scopus subject areas

    • Materials Science(all)
    • Engineering(all)
    • Physics and Astronomy(all)

    Cite this

    Spontaneous Crack Healing in Nanostructured Silica-Based Thin Films. / Itoh, Shun; Kodama, Satoshi; Kobayashi, Maho; Hara, Shintaro; Wada, Hiroaki; Kuroda, Kazuyuki; Shimojima, Atsushi.

    In: ACS Nano, Vol. 11, No. 10, 24.10.2017, p. 10289-10294.

    Research output: Contribution to journalArticle

    Itoh, Shun ; Kodama, Satoshi ; Kobayashi, Maho ; Hara, Shintaro ; Wada, Hiroaki ; Kuroda, Kazuyuki ; Shimojima, Atsushi. / Spontaneous Crack Healing in Nanostructured Silica-Based Thin Films. In: ACS Nano. 2017 ; Vol. 11, No. 10. pp. 10289-10294.
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