Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture

Kazufumi Kawahara, Yoshiaki Hagiwara, Atsushi Shimojima, Kazuyuki Kuroda

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    Trimethylsilylation of a triethoxysilylated derivative of double-four-ring (D4R) silicate led to the formation of a novel crystalline spherical siloxane molecule containing a cubic D4R core, which proves that this bottom-up process provides a new pathway to prepare silica nanoparticles with well defined size, structure, morphology, and functionality.

    Original languageEnglish
    Pages (from-to)3193-3195
    Number of pages3
    JournalJournal of Materials Chemistry
    Volume18
    Issue number27
    DOIs
    Publication statusPublished - 2008

    Fingerprint

    Siloxanes
    Silicates
    siloxanes
    Silicon Dioxide
    silicates
    Silica
    Nanoparticles
    silicon dioxide
    Crystalline materials
    Derivatives
    nanoparticles
    Molecules
    rings
    molecules

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Materials Chemistry
    • Materials Science(all)

    Cite this

    Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture. / Kawahara, Kazufumi; Hagiwara, Yoshiaki; Shimojima, Atsushi; Kuroda, Kazuyuki.

    In: Journal of Materials Chemistry, Vol. 18, No. 27, 2008, p. 3193-3195.

    Research output: Contribution to journalArticle

    @article{9f83fafb0afa47bfb856f493b9f8ccc7,
    title = "Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture",
    abstract = "Trimethylsilylation of a triethoxysilylated derivative of double-four-ring (D4R) silicate led to the formation of a novel crystalline spherical siloxane molecule containing a cubic D4R core, which proves that this bottom-up process provides a new pathway to prepare silica nanoparticles with well defined size, structure, morphology, and functionality.",
    author = "Kazufumi Kawahara and Yoshiaki Hagiwara and Atsushi Shimojima and Kazuyuki Kuroda",
    year = "2008",
    doi = "10.1039/b807533f",
    language = "English",
    volume = "18",
    pages = "3193--3195",
    journal = "Journal of Materials Chemistry",
    issn = "0959-9428",
    publisher = "Royal Society of Chemistry",
    number = "27",

    }

    TY - JOUR

    T1 - Stepwise silylation of double-four-ring (D4R) silicate into a novel spherical siloxane with a defined architecture

    AU - Kawahara, Kazufumi

    AU - Hagiwara, Yoshiaki

    AU - Shimojima, Atsushi

    AU - Kuroda, Kazuyuki

    PY - 2008

    Y1 - 2008

    N2 - Trimethylsilylation of a triethoxysilylated derivative of double-four-ring (D4R) silicate led to the formation of a novel crystalline spherical siloxane molecule containing a cubic D4R core, which proves that this bottom-up process provides a new pathway to prepare silica nanoparticles with well defined size, structure, morphology, and functionality.

    AB - Trimethylsilylation of a triethoxysilylated derivative of double-four-ring (D4R) silicate led to the formation of a novel crystalline spherical siloxane molecule containing a cubic D4R core, which proves that this bottom-up process provides a new pathway to prepare silica nanoparticles with well defined size, structure, morphology, and functionality.

    UR - http://www.scopus.com/inward/record.url?scp=46449119651&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=46449119651&partnerID=8YFLogxK

    U2 - 10.1039/b807533f

    DO - 10.1039/b807533f

    M3 - Article

    AN - SCOPUS:46449119651

    VL - 18

    SP - 3193

    EP - 3195

    JO - Journal of Materials Chemistry

    JF - Journal of Materials Chemistry

    SN - 0959-9428

    IS - 27

    ER -