Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates

Kohei Endo, Munenao Hirokami, Takanori Shibata

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Abstract

The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.

Original languageEnglish
Pages (from-to)3469-3472
Number of pages4
JournalJournal of Organic Chemistry
Volume75
Issue number10
DOIs
Publication statusPublished - 2010 May 21

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ASJC Scopus subject areas

  • Organic Chemistry

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