Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates

Kohei Endo; Munenao Hirokami; Takanori Shibata

doi:10.1021/jo1003407

Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates

Kohei Endo^*, Munenao Hirokami, Takanori Shibata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

102 Citations (Scopus)

Abstract

The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.

Original language	English
Pages (from-to)	3469-3472
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	75
Issue number	10
DOIs	https://doi.org/10.1021/jo1003407
Publication status	Published - 2010 May 21

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo1003407

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title = "Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates",

abstract = "The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.",

author = "Kohei Endo and Munenao Hirokami and Takanori Shibata",

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journal = "Journal of Organic Chemistry",

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AU - Endo, Kohei

AU - Hirokami, Munenao

AU - Shibata, Takanori

PY - 2010/5/21

Y1 - 2010/5/21

N2 - The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.

AB - The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.

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U2 - 10.1021/jo1003407

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JF - Journal of Organic Chemistry

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ER -

Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates

Abstract

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