Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates

Kohei Endo, Munenao Hirokami, Takanori Shibata

    Research output: Contribution to journalArticle

    82 Citations (Scopus)

    Abstract

    The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.

    Original languageEnglish
    Pages (from-to)3469-3472
    Number of pages4
    JournalJournal of Organic Chemistry
    Volume75
    Issue number10
    DOIs
    Publication statusPublished - 2010 May 21

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    Carbonyl compounds
    Addition reactions
    Alkenes

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates. / Endo, Kohei; Hirokami, Munenao; Shibata, Takanori.

    In: Journal of Organic Chemistry, Vol. 75, No. 10, 21.05.2010, p. 3469-3472.

    Research output: Contribution to journalArticle

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