Stimuli-responsive binary mixed polymer brushes and free-standing films by LbL-SIP

Nicel C. Estillore, Rigoberto C. Advincula

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

We report a facile approach to preparing binary mixed polymer brushes and free-standing films by combining the layer-by-layer and surface-initiated polymerization (LbLSIP) techniques. Specifically, the grafting of mixed polymer brushes of poly(n-isopropylacrylamide) and polystyrene (pNIPAM-pSt) onto LbL-macroinitiator-modified planar substrates is described. Atom transfer radical polymerization (ATRP) and free radical polymerization (FRP) techniques were employed for the syntheses of pNIPAM and pSt, respectively, yielding pNIPAM-pSt mixed polymer brushes. The composition of the two polymers was controlled by varying the number of macroinitiator layers deposited on the substrate (i.e., LbL layers = 4, 8, 12, 16, and 20); consequently, mixed brushes of different thicknesses and composition ratios were obtained. Moreover, the switching behavior of the LbL-mixed brush films as a function of solvent and temperature was demonstrated and evaluated by water contact angle and atomic force microscopy (AFM) experiments. It was found that both the solvent and temperature stimuli responses were a function of the mixed brush composition and thickness ratio where the dominant component played a larger role in the response behavior. Furthermore, the ability to obtain free-standing films was exploited. The LbL technique provided the macroinitiator density variation necessary for the preparation of stable free-standing mixed brush films. Specifically, the free-standing films exhibited the rigidity to withstand changes in the solvent and temperature environment and at the same time were flexible enough to respond accordingly to external stimuli.

Original languageEnglish
Pages (from-to)5997-6008
Number of pages12
JournalLangmuir
Volume27
Issue number10
DOIs
Publication statusPublished - 2011 Jun 1
Externally publishedYes

Fingerprint

brushes
Brushes
stimuli
Polymers
polymers
polymerization
Polystyrenes
polystyrene
Chemical analysis
thickness ratio
Atom transfer radical polymerization
Substrates
Free radical polymerization
rigidity
Rigidity
free radicals
Temperature
Contact angle
temperature
Atomic force microscopy

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

Cite this

Stimuli-responsive binary mixed polymer brushes and free-standing films by LbL-SIP. / Estillore, Nicel C.; Advincula, Rigoberto C.

In: Langmuir, Vol. 27, No. 10, 01.06.2011, p. 5997-6008.

Research output: Contribution to journalArticle

Estillore, Nicel C. ; Advincula, Rigoberto C. / Stimuli-responsive binary mixed polymer brushes and free-standing films by LbL-SIP. In: Langmuir. 2011 ; Vol. 27, No. 10. pp. 5997-6008.
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