Structural control of multilayered inorganic-organic hybrids derived from mixtures of alkyltriethoxysilane and tetraethoxysilane

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    Abstract

    Multilayered inorganic-organic hybrids were prepared by cohydrolysis and polycondensation of alkyltriethoxysilanes (CnTES, n = 8-18) and tetraethoxysilane (TEOS). Thin films were deposited from homogeneous solutions containing the oligomeric species by dip-coating. Self-assembly of co-condensed oligomers into lamellar structures depended essentially on the alkyl chain length of CnTES and the temperature of the solutions. By controlling the solution temperature during the dip-coating process, transparent and highly ordered films were formed from the mixtures of TEOS and CnTES with various alkyl chain lengths. The resulting hybrid materials were structurally different from those derived from CnTES alone and exhibited various interlayer structures depending on the alkyl chain length, which is due to the differences in the arrangements and conformations of the chains.

    Original languageEnglish
    Pages (from-to)1144-1149
    Number of pages6
    JournalLangmuir
    Volume18
    Issue number4
    DOIs
    Publication statusPublished - 2002 Feb 19

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    Chain length
    coating
    Polymers
    Coatings
    Lamellar structures
    Hybrid materials
    Polycondensation
    oligomers
    Oligomers
    Self assembly
    Conformations
    self assembly
    interlayers
    Thin films
    Temperature
    temperature
    thin films
    tetraethoxysilane

    ASJC Scopus subject areas

    • Colloid and Surface Chemistry
    • Physical and Theoretical Chemistry

    Cite this

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    title = "Structural control of multilayered inorganic-organic hybrids derived from mixtures of alkyltriethoxysilane and tetraethoxysilane",
    abstract = "Multilayered inorganic-organic hybrids were prepared by cohydrolysis and polycondensation of alkyltriethoxysilanes (CnTES, n = 8-18) and tetraethoxysilane (TEOS). Thin films were deposited from homogeneous solutions containing the oligomeric species by dip-coating. Self-assembly of co-condensed oligomers into lamellar structures depended essentially on the alkyl chain length of CnTES and the temperature of the solutions. By controlling the solution temperature during the dip-coating process, transparent and highly ordered films were formed from the mixtures of TEOS and CnTES with various alkyl chain lengths. The resulting hybrid materials were structurally different from those derived from CnTES alone and exhibited various interlayer structures depending on the alkyl chain length, which is due to the differences in the arrangements and conformations of the chains.",
    author = "Atsushi Shimojima and Kazuyuki Kuroda",
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    T1 - Structural control of multilayered inorganic-organic hybrids derived from mixtures of alkyltriethoxysilane and tetraethoxysilane

    AU - Shimojima, Atsushi

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    N2 - Multilayered inorganic-organic hybrids were prepared by cohydrolysis and polycondensation of alkyltriethoxysilanes (CnTES, n = 8-18) and tetraethoxysilane (TEOS). Thin films were deposited from homogeneous solutions containing the oligomeric species by dip-coating. Self-assembly of co-condensed oligomers into lamellar structures depended essentially on the alkyl chain length of CnTES and the temperature of the solutions. By controlling the solution temperature during the dip-coating process, transparent and highly ordered films were formed from the mixtures of TEOS and CnTES with various alkyl chain lengths. The resulting hybrid materials were structurally different from those derived from CnTES alone and exhibited various interlayer structures depending on the alkyl chain length, which is due to the differences in the arrangements and conformations of the chains.

    AB - Multilayered inorganic-organic hybrids were prepared by cohydrolysis and polycondensation of alkyltriethoxysilanes (CnTES, n = 8-18) and tetraethoxysilane (TEOS). Thin films were deposited from homogeneous solutions containing the oligomeric species by dip-coating. Self-assembly of co-condensed oligomers into lamellar structures depended essentially on the alkyl chain length of CnTES and the temperature of the solutions. By controlling the solution temperature during the dip-coating process, transparent and highly ordered films were formed from the mixtures of TEOS and CnTES with various alkyl chain lengths. The resulting hybrid materials were structurally different from those derived from CnTES alone and exhibited various interlayer structures depending on the alkyl chain length, which is due to the differences in the arrangements and conformations of the chains.

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