Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1246/cl.2007.866

Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta, Kenichi Oyaizu, Hiroyuki Nishide

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp ² character of nitrogens which is intermediate between the purely sp ² and sp ³ nitrogens in oxoammonium cations and amines, respectively.

Original language	English
Pages (from-to)	866-867
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	7
DOIs	https://doi.org/10.1246/cl.2007.866
Publication status	Published - 2007 Jul 5

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.",

author = "Yasunori Yonekuta and Kenichi Oyaizu and Hiroyuki Nishide",

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AB - Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

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