Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta, Kenichi Oyaizu, Hiroyuki Nishide

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

Original languageEnglish
Pages (from-to)866-867
Number of pages2
JournalChemistry Letters
Volume36
Issue number7
DOIs
Publication statusPublished - 2007 Jul 5

ASJC Scopus subject areas

  • Chemistry(all)

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