Structural order and disorder in Co-based layered cuprates CoSr 2(Y,Ce)sCu2O5+2s (s=1-3)

T. Nagai, V. P.S. Awana, E. Takayama-Muromachi, A. Yamazaki, M. Karppinen, H. Yamauchi, S. K. Malik, W. B. Yelon, Y. Matsui

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Abstract

Crystal structures of a homologous series of Co-based layered cuprates, CoSr2(Y,Ce)sCu2O5+2s (s=1-3), have been investigated by high-resolution electron microscopy (HREM) and electron diffraction (ED) techniques. For all the three phases ED patterns showed double periodicity along a direction parallel to the CoO layers, indicating a regular alternation of two types of CoO4-tetrahedra chains within the layers. Also seen was ordering of the chains along the layer-stacking direction for the s=1 phase (Co-1212); ED patterns simulated based on the proposed superstructure model well reproduced the observed patterns. For the s=2 (Co-1222) and s=3 (Co-1232) phases in which an additional fluorite-type layer-block is inserted between two CuO2 planes, HREM and ED analysis revealed complete disorder of the CoO4 chains along the layer-stacking direction. This implies that the interlayer ordering is mainly controlled by the distance between the neighboring CoO layers.

Original languageEnglish
Pages (from-to)213-220
Number of pages8
JournalJournal of Solid State Chemistry
Volume176
Issue number1
DOIs
Publication statusPublished - 2003 Nov 15

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Keywords

  • Co-based cuprates
  • Electron diffraction
  • Fluorite-type block
  • High-resolution electron microscopy
  • Superstructure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Nagai, T., Awana, V. P. S., Takayama-Muromachi, E., Yamazaki, A., Karppinen, M., Yamauchi, H., Malik, S. K., Yelon, W. B., & Matsui, Y. (2003). Structural order and disorder in Co-based layered cuprates CoSr 2(Y,Ce)sCu2O5+2s (s=1-3). Journal of Solid State Chemistry, 176(1), 213-220. https://doi.org/10.1016/S0022-4596(03)00412-2