TY - JOUR
T1 - Structures and magnetic properties of copper(II) complexes containing tetrakis(2-pyridyl)methane
AU - Okazawa, Atsushi
AU - Ishida, Takayuki
AU - Nogami, Takashi
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas of “Molecular Conductors” (No. 15073101) and by Grants-in-Aid for Scientific Research (Nos. 16550121 and 15550115) from the Ministry of Education, Culture, Sports, Science and Technology, Japan. One of the authors (T.I.) thanks Research Foundation For Materials Science, Japan.
PY - 2005/11/17
Y1 - 2005/11/17
N2 - We designed spiro-fused dinculear complexes using tetrakis(2-pyridyl) methane (py4C) for the development of ground high-spin molecules. We attempted to prepare a dinuclear copper(II) complex [{Cu(hfac)2} 2(py4C)], where hfac stands for 1,1,1,5,5,5- hexafluoropentane-2,4-dionate, but we obtained [Cu(hfac)2(py 4C)] and [Cu(hfac)(py4C)·Cu(hfac)3]. These molecular structures were determined by the X-ray crystal structure analysis.
AB - We designed spiro-fused dinculear complexes using tetrakis(2-pyridyl) methane (py4C) for the development of ground high-spin molecules. We attempted to prepare a dinuclear copper(II) complex [{Cu(hfac)2} 2(py4C)], where hfac stands for 1,1,1,5,5,5- hexafluoropentane-2,4-dionate, but we obtained [Cu(hfac)2(py 4C)] and [Cu(hfac)(py4C)·Cu(hfac)3]. These molecular structures were determined by the X-ray crystal structure analysis.
KW - Crystal structure
KW - Magnetic interaction
KW - Spiro compound
UR - http://www.scopus.com/inward/record.url?scp=27644523698&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=27644523698&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2005.03.155
DO - 10.1016/j.poly.2005.03.155
M3 - Article
AN - SCOPUS:27644523698
SN - 0277-5387
VL - 24
SP - 2584
EP - 2587
JO - Polyhedron
JF - Polyhedron
IS - 16-17
ER -