Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques

Xizheng Liu, De Li, Huiqiao Li, Akira Iyo, Nobuko Hanada, Masayoshi Ishida, Haoshen Zhou

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Capacity fading mechanism of pristine and FePO4-coated LiNi1/3Co1/3Mn1/3O2 has been studied by electrochemical and magnetic methods. Along with cycles, significant increase of cell polarization and charger transfer resistance (Rct), which mainly cause the capacity fading at the initial charge/discharge cycles, have been observed according to the cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analysis. In comparison, the existence of FePO4 coating layer can effectively suppress the deterioration of surface polarization and increase of Rct at the interface of electrode/electrolyte. The coated sample suppress the decrease of Li+ diffusion coefficient with prolonged cycles according to the galvanostatic intermittent titration technique (GITT) tests. It also shows larger Weiss constants (fitting above 130 K) and lower blocking temperatures, which indicate the surface coating can suppress the deterioration of Li/Ni disorder upon repeated cycles. This study may give the researchers some light on understanding the capacity fading mechanism of LiNi1/3Co1/3Mn1/3O2 and the effects of surface coating layer, and thus, give help to the future designing of superior coating layers for layered cathode materials in Li-ion batteries.

Original languageEnglish
Pages (from-to)26-32
Number of pages7
JournalElectrochimica Acta
Volume148
DOIs
Publication statusPublished - 2014 Dec 1
Externally publishedYes

Fingerprint

Coatings
Deterioration
Polarization
Electrochemical impedance spectroscopy
Titration
Electrolytes
Cyclic voltammetry
Cathodes
Electrodes
ferric phosphate
Temperature
Lithium-ion batteries

Keywords

  • capacity fading
  • electrochemical
  • Li/Ni disorder
  • magnetic
  • surface coating

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

Cite this

Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques. / Liu, Xizheng; Li, De; Li, Huiqiao; Iyo, Akira; Hanada, Nobuko; Ishida, Masayoshi; Zhou, Haoshen.

In: Electrochimica Acta, Vol. 148, 01.12.2014, p. 26-32.

Research output: Contribution to journalArticle

Liu, Xizheng ; Li, De ; Li, Huiqiao ; Iyo, Akira ; Hanada, Nobuko ; Ishida, Masayoshi ; Zhou, Haoshen. / Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques. In: Electrochimica Acta. 2014 ; Vol. 148. pp. 26-32.
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