Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Keren Zhang, Kevin J. Drummey, Nicholas G. Moon, William D. Chiang, Timothy Edward Long

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

Original languageEnglish
Pages (from-to)3370-3374
Number of pages5
JournalPolymer Chemistry
Volume7
Issue number20
DOIs
Publication statusPublished - 2016 May 28
Externally publishedYes

Fingerprint

Bearings (structural)
Polymers
Ionomers
Salts
Monomers
Free radical polymerization
Homopolymerization
Ammonium Compounds
Polymerization
Free Radicals
Cations
Copolymers
Positive ions
triethylenediamine

ASJC Scopus subject areas

  • Bioengineering
  • Biochemistry
  • Biomedical Engineering
  • Polymers and Plastics
  • Organic Chemistry

Cite this

Zhang, K., Drummey, K. J., Moon, N. G., Chiang, W. D., & Long, T. E. (2016). Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers. Polymer Chemistry, 7(20), 3370-3374. https://doi.org/10.1039/c6py00426a

Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers. / Zhang, Keren; Drummey, Kevin J.; Moon, Nicholas G.; Chiang, William D.; Long, Timothy Edward.

In: Polymer Chemistry, Vol. 7, No. 20, 28.05.2016, p. 3370-3374.

Research output: Contribution to journalArticle

Zhang, K, Drummey, KJ, Moon, NG, Chiang, WD & Long, TE 2016, 'Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers', Polymer Chemistry, vol. 7, no. 20, pp. 3370-3374. https://doi.org/10.1039/c6py00426a
Zhang, Keren ; Drummey, Kevin J. ; Moon, Nicholas G. ; Chiang, William D. ; Long, Timothy Edward. / Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers. In: Polymer Chemistry. 2016 ; Vol. 7, No. 20. pp. 3370-3374.
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