Abstract
Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.
| Original language | English |
|---|---|
| Pages (from-to) | 9016-9019 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 64 |
| DOIs | |
| Publication status | Published - 2017 |
Fingerprint
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes. / Shibata, Takanori; Mitake, Akihito; Akiyama, Yosuke; Kanyiva, Stephen Kyalo.
In: Chemical Communications, Vol. 53, No. 64, 2017, p. 9016-9019.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes
AU - Shibata, Takanori
AU - Mitake, Akihito
AU - Akiyama, Yosuke
AU - Kanyiva, Stephen Kyalo
PY - 2017
Y1 - 2017
N2 - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.
AB - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.
UR - http://www.scopus.com/inward/record.url?scp=85027192802&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85027192802&partnerID=8YFLogxK
U2 - 10.1039/c7cc04997h
DO - 10.1039/c7cc04997h
M3 - Article
AN - SCOPUS:85027192802
VL - 53
SP - 9016
EP - 9019
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 64
ER -