Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

Takanori Shibata, Akihito Mitake, Yosuke Akiyama, Stephen Kyalo Kanyiva

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

Original languageEnglish
Pages (from-to)9016-9019
Number of pages4
JournalChemical Communications
Volume53
Issue number64
DOIs
Publication statusPublished - 2017

Fingerprint

Alkynes
Sulfur
Carbon
Sulfides
Atoms

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes. / Shibata, Takanori; Mitake, Akihito; Akiyama, Yosuke; Kanyiva, Stephen Kyalo.

In: Chemical Communications, Vol. 53, No. 64, 2017, p. 9016-9019.

Research output: Contribution to journalArticle

@article{b34b1a9ca6d3425fbee3ee4cdb5e3221,
title = "Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes",
abstract = "Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.",
author = "Takanori Shibata and Akihito Mitake and Yosuke Akiyama and Kanyiva, {Stephen Kyalo}",
year = "2017",
doi = "10.1039/c7cc04997h",
language = "English",
volume = "53",
pages = "9016--9019",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "64",

}

TY - JOUR

T1 - Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

AU - Shibata, Takanori

AU - Mitake, Akihito

AU - Akiyama, Yosuke

AU - Kanyiva, Stephen Kyalo

PY - 2017

Y1 - 2017

N2 - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

AB - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

UR - http://www.scopus.com/inward/record.url?scp=85027192802&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85027192802&partnerID=8YFLogxK

U2 - 10.1039/c7cc04997h

DO - 10.1039/c7cc04997h

M3 - Article

AN - SCOPUS:85027192802

VL - 53

SP - 9016

EP - 9019

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 64

ER -