Abstract
Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.
| Original language | English |
|---|---|
| Pages (from-to) | 9016-9019 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 64 |
| DOIs | |
| Publication status | Published - 2017 Jan 1 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Shibata, T., Mitake, A., Akiyama, Y., & Kanyiva, K. S. (2017). Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes. Chemical Communications, 53(64), 9016-9019. https://doi.org/10.1039/c7cc04997h