Abstract
The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.
| Original language | English |
|---|---|
| Pages (from-to) | 401-405 |
| Number of pages | 5 |
| Journal | Polymers for Advanced Technologies |
| Volume | 3 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 1992 |
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Keywords
- Diphenyl sulfide
- Disulfide bond
- Oligo(phenylene sulfide)
- Polymeric aromatic sulfur compound
- Sulfur dichloride
ASJC Scopus subject areas
- Polymers and Plastics
Cite this
Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides. / Miyatake, Kenji; Jikei, Mitsutoshi; Yamamoto, Kimihisa; Nishide, Hiroyuki; Tsuchida, Eishun.
In: Polymers for Advanced Technologies, Vol. 3, No. 7, 1992, p. 401-405.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides
AU - Miyatake, Kenji
AU - Jikei, Mitsutoshi
AU - Yamamoto, Kimihisa
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1992
Y1 - 1992
N2 - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.
AB - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.
KW - Diphenyl sulfide
KW - Disulfide bond
KW - Oligo(phenylene sulfide)
KW - Polymeric aromatic sulfur compound
KW - Sulfur dichloride
UR - http://www.scopus.com/inward/record.url?scp=84994941982&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84994941982&partnerID=8YFLogxK
U2 - 10.1002/pat.1992.220030706
DO - 10.1002/pat.1992.220030706
M3 - Article
VL - 3
SP - 401
EP - 405
JO - Polymers for Advanced Technologies
JF - Polymers for Advanced Technologies
SN - 1042-7147
IS - 7
ER -