Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Kenji Miyatake; Mitsutoshi Jikei; Kimihisa Yamamoto; Hiroyuki Nishide; Eishun Tsuchida

doi:10.1002/pat.1992.220030706

Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Kenji Miyatake, Mitsutoshi Jikei, Kimihisa Yamamoto, Hiroyuki Nishide, Eishun Tsuchida

Graduate School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

Original language	English
Pages (from-to)	401-405
Number of pages	5
Journal	Polymers for Advanced Technologies
Volume	3
Issue number	7
DOIs	https://doi.org/10.1002/pat.1992.220030706
Publication status	Published - 1992

Keywords

Diphenyl sulfide
Disulfide bond
Oligo(phenylene sulfide)
Polymeric aromatic sulfur compound
Sulfur dichloride

ASJC Scopus subject areas

Polymers and Plastics

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10.1002/pat.1992.220030706

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title = "Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides",

abstract = "The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.",

keywords = "Diphenyl sulfide, Disulfide bond, Oligo(phenylene sulfide), Polymeric aromatic sulfur compound, Sulfur dichloride",

author = "Kenji Miyatake and Mitsutoshi Jikei and Kimihisa Yamamoto and Hiroyuki Nishide and Eishun Tsuchida",

year = "1992",

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language = "English",

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T1 - Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

AU - Miyatake, Kenji

AU - Jikei, Mitsutoshi

AU - Yamamoto, Kimihisa

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

PY - 1992

Y1 - 1992

N2 - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

AB - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

KW - Diphenyl sulfide

KW - Disulfide bond

KW - Oligo(phenylene sulfide)

KW - Polymeric aromatic sulfur compound

KW - Sulfur dichloride

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DO - 10.1002/pat.1992.220030706

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EP - 405

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