Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Kenji Miyatake, Mitsutoshi Jikei, Kimihisa Yamamoto, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

Original languageEnglish
Pages (from-to)401-405
Number of pages5
JournalPolymers for Advanced Technologies
Volume3
Issue number7
DOIs
Publication statusPublished - 1992

Fingerprint

Sulfur
Polymers
Sulfides
Powders
Disulfides
Chemical activation
diphenyl sulfide
sulfur monochloride
Temperature

Keywords

  • Diphenyl sulfide
  • Disulfide bond
  • Oligo(phenylene sulfide)
  • Polymeric aromatic sulfur compound
  • Sulfur dichloride

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides. / Miyatake, Kenji; Jikei, Mitsutoshi; Yamamoto, Kimihisa; Nishide, Hiroyuki; Tsuchida, Eishun.

In: Polymers for Advanced Technologies, Vol. 3, No. 7, 1992, p. 401-405.

Research output: Contribution to journalArticle

Miyatake, Kenji ; Jikei, Mitsutoshi ; Yamamoto, Kimihisa ; Nishide, Hiroyuki ; Tsuchida, Eishun. / Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides. In: Polymers for Advanced Technologies. 1992 ; Vol. 3, No. 7. pp. 401-405.
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