Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Kenji Miyatake; Mitsutoshi Jikei; Kimihisa Yamamoto; Hiroyuki Nishide; Eishun Tsuchida

doi:10.1002/pat.1992.220030706

Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Kenji Miyatake^*, Mitsutoshi Jikei, Kimihisa Yamamoto, Hiroyuki Nishide, Eishun Tsuchida

^*Corresponding author for this work

Graduate School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

Original language	English
Pages (from-to)	401-405
Number of pages	5
Journal	Polymers for Advanced Technologies
Volume	3
Issue number	7
DOIs	https://doi.org/10.1002/pat.1992.220030706
Publication status	Published - 1992

Keywords

Diphenyl sulfide
Disulfide bond
Oligo(phenylene sulfide)
Polymeric aromatic sulfur compound
Sulfur dichloride

ASJC Scopus subject areas

Polymers and Plastics

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10.1002/pat.1992.220030706

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title = "Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides",

abstract = "The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.",

keywords = "Diphenyl sulfide, Disulfide bond, Oligo(phenylene sulfide), Polymeric aromatic sulfur compound, Sulfur dichloride",

author = "Kenji Miyatake and Mitsutoshi Jikei and Kimihisa Yamamoto and Hiroyuki Nishide and Eishun Tsuchida",

year = "1992",

doi = "10.1002/pat.1992.220030706",

language = "English",

volume = "3",

pages = "401--405",

journal = "Polymers for Advanced Technologies",

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TY - JOUR

T1 - Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

AU - Miyatake, Kenji

AU - Jikei, Mitsutoshi

AU - Yamamoto, Kimihisa

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

PY - 1992

Y1 - 1992

N2 - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

AB - The electrophilic reaction of sulfur dichloride with diphenyl sulfide proceeds efficiently at room temperature to yield oligo(phenylene sulfide) in the presence of a catalytic amount of Fe powder. Sulfur dichloride shows higher reactivity than sulfur monochloride. The reaction is promoted through the activation of sulfur dichloride by Fe powder. The polymeric product contains a linear structure linked by disulfide and sulfide bonds.

KW - Diphenyl sulfide

KW - Disulfide bond

KW - Oligo(phenylene sulfide)

KW - Polymeric aromatic sulfur compound

KW - Sulfur dichloride

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U2 - 10.1002/pat.1992.220030706

DO - 10.1002/pat.1992.220030706

M3 - Article

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SP - 401

EP - 405

JO - Polymers for Advanced Technologies

JF - Polymers for Advanced Technologies

SN - 1042-7147

IS - 7

ER -

Sulfur‐containing polymers by the reaction of diphenyl sulfide with sulfur chlorides

Abstract

Keywords

ASJC Scopus subject areas

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