13C-NMR Study of Acid Dissociation Constant (pKa) Effects on the CO2 Absorption and Regeneration of Aqueous Alkanolpiperidine

Yukio Furukawa, Hirotaka Koriki, Daiki Shuto, Hiroshi Sato, Yasuro Yamanaka

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    We have studied the formation rates of HCO3 -/CO3 2-, amine/protonated amine, carbamate/protonated carbamate, and carbonate/protonated carbonate in the course of CO2 absorption at room temperature, and composition changes and CO2 release upon heating at 93 °C for 30 min for aqueous solutions of 9 kinds of alkanolpiperidines using 13C-NMR spectroscopy. The pKa values of these alkanolpiperidines were measured. The initial CO2 capture rates of alkanolpiperidines do not depend on their pKa values, which is quite different from general trends of aqueous amine absorbents. The CO2 release amount of each alkanolpiperidine increased with decreasing pKa, as a general trend. The CO2 release amounts of 1-HE-PD, 2-HM-1-M-PD, 3-HM-1-M-PD, and 4-HM-1-M-PD increased with increasing concentrations.

    Original languageEnglish
    Pages (from-to)1765-1771
    Number of pages7
    JournalEnergy Procedia
    Volume114
    DOIs
    Publication statusPublished - 2017

    Fingerprint

    Amines
    Nuclear magnetic resonance
    Acids
    Carbonates
    Nuclear magnetic resonance spectroscopy
    Heating
    Chemical analysis
    Temperature

    Keywords

    • C-NMR
    • acid dissociation constant
    • alkanolpiperidine
    • CO capture
    • CO regeneration

    ASJC Scopus subject areas

    • Energy(all)

    Cite this

    13C-NMR Study of Acid Dissociation Constant (pKa) Effects on the CO2 Absorption and Regeneration of Aqueous Alkanolpiperidine. / Furukawa, Yukio; Koriki, Hirotaka; Shuto, Daiki; Sato, Hiroshi; Yamanaka, Yasuro.

    In: Energy Procedia, Vol. 114, 2017, p. 1765-1771.

    Research output: Contribution to journalArticle

    Furukawa, Yukio ; Koriki, Hirotaka ; Shuto, Daiki ; Sato, Hiroshi ; Yamanaka, Yasuro. / 13C-NMR Study of Acid Dissociation Constant (pKa) Effects on the CO2 Absorption and Regeneration of Aqueous Alkanolpiperidine. In: Energy Procedia. 2017 ; Vol. 114. pp. 1765-1771.
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    AU - Shuto, Daiki

    AU - Sato, Hiroshi

    AU - Yamanaka, Yasuro

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    AB - We have studied the formation rates of HCO3 -/CO3 2-, amine/protonated amine, carbamate/protonated carbamate, and carbonate/protonated carbonate in the course of CO2 absorption at room temperature, and composition changes and CO2 release upon heating at 93 °C for 30 min for aqueous solutions of 9 kinds of alkanolpiperidines using 13C-NMR spectroscopy. The pKa values of these alkanolpiperidines were measured. The initial CO2 capture rates of alkanolpiperidines do not depend on their pKa values, which is quite different from general trends of aqueous amine absorbents. The CO2 release amount of each alkanolpiperidine increased with decreasing pKa, as a general trend. The CO2 release amounts of 1-HE-PD, 2-HM-1-M-PD, 3-HM-1-M-PD, and 4-HM-1-M-PD increased with increasing concentrations.

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