Suppression of Sulfur Segregation at Scale/Substrate Interface for Sixth-Generation Single-Crystal Ni-Base Superalloy

Kyoko Kawagishi, Chihiro Tabata, Takuya Sugiyama, Tadaharu Yokokawa, Jun Uzuhashi, Tadakatsu Ohkubo, Yuji Takata, Michinari Yuyama, Shinsuke Suzuki, Hiroshi Harada

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

It is known that a single-crystal Ni-base superalloy containing a trace amount of sulfur has reduced high-temperature oxidation resistance. Our previous study has shown that melting of Ni-base superalloys in a CaO crucible can eliminate the effect of sulfur on oxidation resistance, but the mechanism was not completely clear. In this study, we finally succeeded in detecting the segregation of sulfur at the oxide/substrate interface of 6th generation single-crystal superalloys using STEM-EDS analysis and confirmed that segregation could be suppressed by melting in the CaO crucible. As a result, it was found that melting in the CaO crucible can improve the oxidation resistance while maintaining the creep characteristics of sixth-generation single-crystal Ni-base superalloy.

Original languageEnglish
Title of host publicationSuperalloys 2020 - Proceedings of the 14th International Symposium on Superalloys
EditorsSammy Tin, Mark Hardy, Justin Clews, Jonathan Cormier, Qiang Feng, John Marcin, Chris O'Brien, Akane Suzuki
PublisherSpringer Science and Business Media Deutschland GmbH
Pages798-803
Number of pages6
ISBN (Print)9783030518332
DOIs
Publication statusPublished - 2020
Event14th International Symposium on Superalloys, Superalloys 2021 - Seven Springs, United States
Duration: 2021 Sep 122021 Sep 16

Publication series

NameMinerals, Metals and Materials Series
ISSN (Print)2367-1181
ISSN (Electronic)2367-1696

Conference

Conference14th International Symposium on Superalloys, Superalloys 2021
CountryUnited States
CitySeven Springs
Period21/9/1221/9/16

Keywords

  • Creep
  • Oxidation
  • Segregation
  • Single-crystal Ni-based superalloy
  • Sulfur

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy Engineering and Power Technology
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

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