Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites

David L. Inglefield, Timothy Edward Long

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Hydrogen bonding functionalities were introduced onto the surface of multi-walled carbon nanotubes (MWCNTs) using acid oxidation to promote intermolecular interactions and facilitate dispersion in polyurethanes matrices. Chemical oxidation was achieved by refluxing with concentrated nitric acid, which introduced carboxylic acid groups onto the MWCNT surface. These surface-bound reactive carboxylic acid groups were further functionalized into amide-amine and amide-urea derivatives, providing an opportunity for additional hydrogen bonding on the surface of the MWCNT. Segmented poly(tetramethylene oxide) based polyurethanes were prepared using methylene bis-(4- cyclohexylisocyanate) (HMDI) as the diisocyanate and 1,4 butanediol as the chain extender. Functionalized MWCNTs were dispersed in a 45 wt% hard segment polyurethane matrix with sonication, and composite film properties were measured to investigate the influence of surface functionality on thermal and mechanical properties. Transmission electron microscopy was also used to investigate the effect of functionalization on the nanotube structure and compare the dispersibility of the different MWCNTs in the polyurethane matrix. Introduction of hydrogen bonding surface functionality led to an increased dispersibility of the MWCNTs and an improvement in mechanical properties. This is in sharp contrast to non-functionalized MWCNT analogs. Improvements in mechanical properties were independent of the chemical structure of the interactive functional groups on the MWCNT surface.

Original languageEnglish
Title of host publicationSPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012
Subtitle of host publicationUnleashing the Power of Design
Pages519-527
Number of pages9
Publication statusPublished - 2012 Dec 1
Externally publishedYes
Event12th Annual Automotive Composites Conference and Exhibition 2012: Unleashing the Power of Design, ACCE 2012 - Troy, MI, United States
Duration: 2012 Sep 112012 Sep 13

Other

Other12th Annual Automotive Composites Conference and Exhibition 2012: Unleashing the Power of Design, ACCE 2012
CountryUnited States
CityTroy, MI
Period12/9/1112/9/13

Fingerprint

Polyurethanes
Carbon nanotubes
Nanocomposites
Hydrogen bonds
Carboxylic acids
Amides
Mechanical properties
Oxidation
Sonication
Composite films
Nitric acid
Urea
Nanotubes
Functional groups
Amines
Thermodynamic properties
Transmission electron microscopy
Derivatives
Oxides
Acids

ASJC Scopus subject areas

  • Automotive Engineering
  • Mechanical Engineering

Cite this

Inglefield, D. L., & Long, T. E. (2012). Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites. In SPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012: Unleashing the Power of Design (pp. 519-527)

Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites. / Inglefield, David L.; Long, Timothy Edward.

SPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012: Unleashing the Power of Design. 2012. p. 519-527.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Inglefield, DL & Long, TE 2012, Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites. in SPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012: Unleashing the Power of Design. pp. 519-527, 12th Annual Automotive Composites Conference and Exhibition 2012: Unleashing the Power of Design, ACCE 2012, Troy, MI, United States, 12/9/11.
Inglefield DL, Long TE. Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites. In SPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012: Unleashing the Power of Design. 2012. p. 519-527
Inglefield, David L. ; Long, Timothy Edward. / Surface functionalization of multi-walled carbon nanotubes with hydrogen bonding functionality for tailored polyurethane nanocomposites. SPE Automotive and Composites Divisions - 12th Annual Automotive Composites Conference and Exhibition 2012, ACCE 2012: Unleashing the Power of Design. 2012. pp. 519-527
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