Abstract
The surface modification of Gd doped ceria (GDC) and Sr- and Mg-codoped lanthanum gallate (LSGM) powders with cationic and anionic polyelectrolytes, Poly(diallyldimethylammonium chloride) (PDDA) and poly(2 -acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS), respevtively, was performed by the Layer by Layer (LbL) adsorption method to improve the surface-charging uniformity. The tri-layer of GDC/LSGM/GDC was deposited on a polypyrrole coated porous NiO-YSZ substrate by sequential EPD using the ethanol-based suspensions of the surface-modified powders. The topcoating of hydroxyl-propyl cellulose (HPC) on the deposited layers was conducted to control the drying rate with suppressing the cracking and peeling-off of the deposits. The advantage of the use of those polymers for the EPD process including the drying technique was demonstrated.
| Original language | English |
|---|---|
| Title of host publication | Electrophoretic Deposition |
| Subtitle of host publication | Fundamentals and Applications V |
| Editors | Aldo R. Boccaccini, Omer Van der Biest, Tetsuo Uchikoshi, James H. Dickerson, B. Ferrari |
| Publisher | Trans Tech Publications Ltd |
| Pages | 255-260 |
| Number of pages | 6 |
| ISBN (Print) | 9783038354970 |
| DOIs | |
| Publication status | Published - 2015 Jan 1 |
| Externally published | Yes |
| Event | 5th International Conference on Electrophoretic Deposition: Fundamentals and Applications, EPD 2014 - Hernstein, Austria Duration: 2014 Oct 5 → 2014 Oct 10 |
Publication series
| Name | Key Engineering Materials |
|---|---|
| Volume | 654 |
| ISSN (Print) | 1013-9826 |
Conference
| Conference | 5th International Conference on Electrophoretic Deposition: Fundamentals and Applications, EPD 2014 |
|---|---|
| Country | Austria |
| City | Hernstein |
| Period | 14/10/5 → 14/10/10 |
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Keywords
- GDC
- Layer by Layer adsorption
- LSGM
- Polyanion
- Polycation
ASJC Scopus subject areas
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering
Cite this
Surface modification of complex oxide powder with polyelectrolyte layers improving EPD characteristics. / Uchikoshi, Tetsuo; Eto, Eiji; Suzuki, Harue T.; Matsunaga, Chika; Kobayashi, Kiyoshi; Suzuki, Tohru; Muto, Hiroyuki; Matsuda, Atsunori.
Electrophoretic Deposition: Fundamentals and Applications V. ed. / Aldo R. Boccaccini; Omer Van der Biest; Tetsuo Uchikoshi; James H. Dickerson; B. Ferrari. Trans Tech Publications Ltd, 2015. p. 255-260 (Key Engineering Materials; Vol. 654).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Surface modification of complex oxide powder with polyelectrolyte layers improving EPD characteristics
AU - Uchikoshi, Tetsuo
AU - Eto, Eiji
AU - Suzuki, Harue T.
AU - Matsunaga, Chika
AU - Kobayashi, Kiyoshi
AU - Suzuki, Tohru
AU - Muto, Hiroyuki
AU - Matsuda, Atsunori
PY - 2015/1/1
Y1 - 2015/1/1
N2 - The surface modification of Gd doped ceria (GDC) and Sr- and Mg-codoped lanthanum gallate (LSGM) powders with cationic and anionic polyelectrolytes, Poly(diallyldimethylammonium chloride) (PDDA) and poly(2 -acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS), respevtively, was performed by the Layer by Layer (LbL) adsorption method to improve the surface-charging uniformity. The tri-layer of GDC/LSGM/GDC was deposited on a polypyrrole coated porous NiO-YSZ substrate by sequential EPD using the ethanol-based suspensions of the surface-modified powders. The topcoating of hydroxyl-propyl cellulose (HPC) on the deposited layers was conducted to control the drying rate with suppressing the cracking and peeling-off of the deposits. The advantage of the use of those polymers for the EPD process including the drying technique was demonstrated.
AB - The surface modification of Gd doped ceria (GDC) and Sr- and Mg-codoped lanthanum gallate (LSGM) powders with cationic and anionic polyelectrolytes, Poly(diallyldimethylammonium chloride) (PDDA) and poly(2 -acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS), respevtively, was performed by the Layer by Layer (LbL) adsorption method to improve the surface-charging uniformity. The tri-layer of GDC/LSGM/GDC was deposited on a polypyrrole coated porous NiO-YSZ substrate by sequential EPD using the ethanol-based suspensions of the surface-modified powders. The topcoating of hydroxyl-propyl cellulose (HPC) on the deposited layers was conducted to control the drying rate with suppressing the cracking and peeling-off of the deposits. The advantage of the use of those polymers for the EPD process including the drying technique was demonstrated.
KW - GDC
KW - Layer by Layer adsorption
KW - LSGM
KW - Polyanion
KW - Polycation
UR - http://www.scopus.com/inward/record.url?scp=84944313346&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84944313346&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/KEM.654.255
DO - 10.4028/www.scientific.net/KEM.654.255
M3 - Conference contribution
SN - 9783038354970
T3 - Key Engineering Materials
SP - 255
EP - 260
BT - Electrophoretic Deposition
A2 - Boccaccini, Aldo R.
A2 - Van der Biest, Omer
A2 - Uchikoshi, Tetsuo
A2 - Dickerson, James H.
A2 - Ferrari, B.
PB - Trans Tech Publications Ltd
ER -