Synthesis and characterization of a novel AB2 monomer and corresponding hyperbranched poly(arylene ether phosphine oxide)s

Qin Lin, Timothy Edward Long

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

A novel AB2 monomer, 4-(fluorophenyl)-4′,4″-(bishydroxyphenyl) phosphine oxide, was synthesized. The monomer was successfully polymerized to a modest molecular weight with various catalysts, including K2CO3 and Cs2CO3/Mg(OH)2. Hyperbranched polymers exhibited exceptionally high thermal stability and solubility in conventional polar organic solvents and basic water solutions.

Original languageEnglish
Pages (from-to)3736-3741
Number of pages6
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume38
Issue number20
DOIs
Publication statusPublished - 2000 Oct 15
Externally publishedYes

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phosphine
Ether
Oxides
Ethers
Monomers
Organic solvents
Polymers
Thermodynamic stability
Solubility
Molecular weight
Catalysts
Water

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

Cite this

Synthesis and characterization of a novel AB2 monomer and corresponding hyperbranched poly(arylene ether phosphine oxide)s. / Lin, Qin; Long, Timothy Edward.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 38, No. 20, 15.10.2000, p. 3736-3741.

Research output: Contribution to journalArticle

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