Synthesis and characterization of microporous layered zirconium phenylphosphonate

N. K. Mal, M. Sasidharan, M. Fujiwara, Y. Yamada, Masahiko Matsukata

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

    Original languageEnglish
    Pages (from-to)1153-1159
    Number of pages7
    JournalStudies in Surface Science and Catalysis
    Volume154 A
    Publication statusPublished - 2004

    Fingerprint

    Zirconium
    synthesis
    Hydroxyl Radical
    Nuclear magnetic resonance
    Ions
    nuclear magnetic resonance
    phenylphosphonic acid
    ions
    Sodium
    spacing
    sodium
    Derivatives

    Keywords

    • Layered
    • Mircroporous material
    • Sodium dodecylsulfate
    • Zirconium phenylphosphonate

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Catalysis

    Cite this

    Synthesis and characterization of microporous layered zirconium phenylphosphonate. / Mal, N. K.; Sasidharan, M.; Fujiwara, M.; Yamada, Y.; Matsukata, Masahiko.

    In: Studies in Surface Science and Catalysis, Vol. 154 A, 2004, p. 1153-1159.

    Research output: Contribution to journalArticle

    Mal, N. K. ; Sasidharan, M. ; Fujiwara, M. ; Yamada, Y. ; Matsukata, Masahiko. / Synthesis and characterization of microporous layered zirconium phenylphosphonate. In: Studies in Surface Science and Catalysis. 2004 ; Vol. 154 A. pp. 1153-1159.
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    abstract = "Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.",
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    AU - Mal, N. K.

    AU - Sasidharan, M.

    AU - Fujiwara, M.

    AU - Yamada, Y.

    AU - Matsukata, Masahiko

    PY - 2004

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    N2 - Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

    AB - Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

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    KW - Mircroporous material

    KW - Sodium dodecylsulfate

    KW - Zirconium phenylphosphonate

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