Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa; Satoru Onaka; Tadashi Yamaguchi; Tasuku Ito; Seiji Watase; Masami Nakamoto

doi:10.1246/bcsj.76.1601

Synthesis and characterization of the Au₁₁ cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa, Satoru Onaka^*, Tadashi Yamaguchi, Tasuku Ito, Seiji Watase, Masami Nakamoto

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A new Au₁₁ cluster with (m-CF₃C₆H ₄)₃P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au₁₁X₃(PR ₃)₇ clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF₃ substituents at a meta-position of each phenyl ring of PR₃ ligands.

Original language	English
Pages (from-to)	1601-1602
Number of pages	2
Journal	Bulletin of the Chemical Society of Japan
Volume	76
Issue number	8
DOIs	https://doi.org/10.1246/bcsj.76.1601
Publication status	Published - 2003 Aug
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/bcsj.76.1601

Cite this

@article{7daa13e5b14b4d41aa26a74f9b24885f,

title = "Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy",

abstract = "A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.",

author = "Keiko Nunokawa and Satoru Onaka and Tadashi Yamaguchi and Tasuku Ito and Seiji Watase and Masami Nakamoto",

year = "2003",

month = aug,

doi = "10.1246/bcsj.76.1601",

language = "English",

volume = "76",

pages = "1601--1602",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "8",

}

TY - JOUR

T1 - Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

AU - Nunokawa, Keiko

AU - Onaka, Satoru

AU - Yamaguchi, Tadashi

AU - Ito, Tasuku

AU - Watase, Seiji

AU - Nakamoto, Masami

PY - 2003/8

Y1 - 2003/8

N2 - A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

AB - A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

UR - http://www.scopus.com/inward/record.url?scp=0041315741&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0041315741&partnerID=8YFLogxK

U2 - 10.1246/bcsj.76.1601

DO - 10.1246/bcsj.76.1601

M3 - Article

AN - SCOPUS:0041315741

VL - 76

SP - 1601

EP - 1602

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

SN - 0009-2673

IS - 8

ER -

Synthesis and characterization of the Au₁₁ cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this