Abstract
A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
| Original language | English |
|---|---|
| Pages (from-to) | 1601-1602 |
| Number of pages | 2 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 76 |
| Issue number | 8 |
| Publication status | Published - 2003 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy. / Nunokawa, Keiko; Onaka, Satoru; Yamaguchi, Tadashi; Ito, Tasuku; Watase, Seiji; Nakamoto, Masami.
In: Bulletin of the Chemical Society of Japan, Vol. 76, No. 8, 2003, p. 1601-1602.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy
AU - Nunokawa, Keiko
AU - Onaka, Satoru
AU - Yamaguchi, Tadashi
AU - Ito, Tasuku
AU - Watase, Seiji
AU - Nakamoto, Masami
PY - 2003
Y1 - 2003
N2 - A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
AB - A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
UR - http://www.scopus.com/inward/record.url?scp=0041315741&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0041315741&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0041315741
VL - 76
SP - 1601
EP - 1602
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
SN - 0009-2673
IS - 8
ER -