Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa, Satoru Onaka, Tadashi Yamaguchi, Tasuku Ito, Seiji Watase, Masami Nakamoto

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

Original languageEnglish
Pages (from-to)1601-1602
Number of pages2
JournalBulletin of the Chemical Society of Japan
Volume76
Issue number8
Publication statusPublished - 2003
Externally publishedYes

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phosphine
X ray photoelectron spectroscopy
Single crystals
Spectroscopy
Ligands
X ray diffraction
X rays

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy. / Nunokawa, Keiko; Onaka, Satoru; Yamaguchi, Tadashi; Ito, Tasuku; Watase, Seiji; Nakamoto, Masami.

In: Bulletin of the Chemical Society of Japan, Vol. 76, No. 8, 2003, p. 1601-1602.

Research output: Contribution to journalArticle

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AU - Nunokawa, Keiko

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AU - Yamaguchi, Tadashi

AU - Ito, Tasuku

AU - Watase, Seiji

AU - Nakamoto, Masami

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