Abstract
A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
| Original language | English |
|---|---|
| Pages (from-to) | 1601-1602 |
| Number of pages | 2 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 76 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2003 Aug |
ASJC Scopus subject areas
- Chemistry(all)
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Nunokawa, K., Onaka, S., Yamaguchi, T., Ito, T., Watase, S., & Nakamoto, M. (2003). Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy. Bulletin of the Chemical Society of Japan, 76(8), 1601-1602. https://doi.org/10.1246/bcsj.76.1601