Synthesis and electrochemical properties of bipyrimidine bridged triruthenium complexes

Hiroyoshi Ohtsu, Jun Kitazume, Tadashi Yamaguchi

    Research output: Contribution to journalArticle

    7 Citations (Scopus)

    Abstract

    A new μ4-bpym-bridged dimer of an oxoacetao-triruthenium complex with carbonyl, [{Ru3O(CH3COO)5(CO)(py)} 24-bpym)], was synthesized. The complex possesses two stable mixed-valence states associated with Ru3 III,III,II/Ru3 III,II,II and Ru3 III,III,III/Ru3 III,III,II. The IR-spectroelectrochemistry reveals ν(CO) spectra in five oxidation states, Ru3 III,III,III-Ru3 III,III,III to Ru3 III,II,II-Ru3 III,II,II and both the mixed-valence states show a spectrum indicating medium interaction between the Ru3 units.

    Original languageEnglish
    Pages (from-to)7502-7504
    Number of pages3
    JournalDalton Transactions
    Volume40
    Issue number29
    DOIs
    Publication statusPublished - 2011 Aug 7

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    Spectroelectrochemistry
    Electrochemical properties
    Dimers
    Oxidation

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Synthesis and electrochemical properties of bipyrimidine bridged triruthenium complexes. / Ohtsu, Hiroyoshi; Kitazume, Jun; Yamaguchi, Tadashi.

    In: Dalton Transactions, Vol. 40, No. 29, 07.08.2011, p. 7502-7504.

    Research output: Contribution to journalArticle

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