@article{c5d485200e574839acc67a5a16b97a43,
title = "Synthesis and magnetic properties of linear two-coordinate monomeric diaryliron(II) complexes bearing fused-ring bulky {"}Rind{"} groups",
abstract = "Monomeric diaryliron(II) complexes, Fe(Rind)2, have been obtained by introducing fused-ring bulky {"}Rind{"} groups. For Fe(Eind)2, a significant orbital contribution of the Fe(II) ion due to the linear two-coordination has been determined by the highly effective magnetic moment (μeff = 5.82 μB) and the extraordinarily large internal hyperfine field (Hn = ca. 140 T) in the M{\"o}ssbauer spectrum. Variable-frequency out-of-phase ac susceptibility data demonstrate an effective spin-reversal barrier of Ueff = 51.2(7) cm-1 associated with the single-ion magnet behavior.",
keywords = "Diaryliron(II) complex, Large internal hyperfine field, Single-ion magnet",
author = "Shun Goda and Masanori Nikai and Mikinao Ito and Daisuke Hashizume and Kohei Tamao and Atsushi Okazawa and Norimichi Kojima and Hiroyuki Fueno and Kazuyoshi Tanaka and Yoshio Kobayashi and Tsukasa Matsuo",
note = "Funding Information: We thank the Ministry of Education, Culture, Sports, Science and Technology of Japan for the Grant-in-Aid for Specially Promoted Research (No. 19002008 for K. Tamao) and Scientific Research on Innovative Areas {"}Stimuli-responsive Chemical Species for the Creation of Functional Molecules{"} [#2408] (No. 24109003 for T.M., and Nos. 25109543 and 15H00964 for D.H.). This study was also partially supported by MEXT-Supported Program for the Strategic Research Foundation at Private Universities 2014-2018 subsidy from MEXT and Kindai University. We are grateful to Materials Characterization Support Unit, RIKEN Center for Emergent Matter Science (CEMS) for the elemental analyses. We thank Dr. Y. Ishii and Dr. I. Watanabe (RIKEN RAL) for their valuable discussions. We also thank Mr. M. Hamura and Dipl.-Chem. N. Hayakawa (Kindai University) for their support. T.M. thanks Professors A. Sudo and T. Nakahodo (Kindai University) for their valuable discussions. Publisher Copyright: {\textcopyright} 2016 The Chemical Society of Japan.",
year = "2016",
doi = "10.1246/cl.160216",
language = "English",
volume = "45",
pages = "634--636",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "6",
}