Synthesis and properties of a new kinetically stabilized digermyne: New insights for a germanium analogue of an alkyne

Yusuke Sugiyama; Takahiro Sasamori; Yoshinobu Hosoi; Yukio Furukawa; Nozomi Takagi; Shigeru Nagase; Norihiro Tokitoh

doi:10.1021/ja057205y

Synthesis and properties of a new kinetically stabilized digermyne: New insights for a germanium analogue of an alkyne

Yusuke Sugiyama, Takahiro Sasamori, Yoshinobu Hosoi, Yukio Furukawa, Nozomi Takagi, Shigeru Nagase, Norihiro Tokitoh

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

137 Citations (Scopus)

Abstract

The reduction of an overcrowded (E)-1,2-dibromodigermene, Bbt(Br)Ge=Ge(Br)Bbt (2) [Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4- [tris(trimethylsilyl)methyl]phenyl], with KC₈ afforded a stable digermyne, BbtGe≡GeBbt (1). The Ge≡Ge triple-bond characters of 1 were revealed by the X-ray crystallographic analysis and spectroscopic studies (UV/vis and Raman spectra) together with theoretical calculations. The Ge≡Ge bond lengths of the two nonidentical molecules of 1 observed in the unit cell were shorter than that of the previously reported digermyne, Ar′e≡GeAr′ (Ar′ = 2,6-Dip₂C₆H ₃, Dip = 2,6-diisopropylphenyl).

Original language	English
Pages (from-to)	1023-1031
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	128
Issue number	3
DOIs	https://doi.org/10.1021/ja057205y
Publication status	Published - 2006 Jan 25

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Sugiyama, Y., Sasamori, T., Hosoi, Y., Furukawa, Y., Takagi, N., Nagase, S., & Tokitoh, N. (2006). Synthesis and properties of a new kinetically stabilized digermyne: New insights for a germanium analogue of an alkyne. Journal of the American Chemical Society, 128(3), 1023-1031. https://doi.org/10.1021/ja057205y

Synthesis and properties of a new kinetically stabilized digermyne : New insights for a germanium analogue of an alkyne. / Sugiyama, Yusuke; Sasamori, Takahiro; Hosoi, Yoshinobu; Furukawa, Yukio; Takagi, Nozomi; Nagase, Shigeru; Tokitoh, Norihiro.

In: Journal of the American Chemical Society, Vol. 128, No. 3, 25.01.2006, p. 1023-1031.

Research output: Contribution to journal › Article

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abstract = "The reduction of an overcrowded (E)-1,2-dibromodigermene, Bbt(Br)Ge=Ge(Br)Bbt (2) [Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4- [tris(trimethylsilyl)methyl]phenyl], with KC8 afforded a stable digermyne, BbtGe≡GeBbt (1). The Ge≡Ge triple-bond characters of 1 were revealed by the X-ray crystallographic analysis and spectroscopic studies (UV/vis and Raman spectra) together with theoretical calculations. The Ge≡Ge bond lengths of the two nonidentical molecules of 1 observed in the unit cell were shorter than that of the previously reported digermyne, Ar′e≡GeAr′ (Ar′ = 2,6-Dip2C6H 3, Dip = 2,6-diisopropylphenyl).",

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