Synthesis and properties of norcaradiene-cycloheptatriene system fused with isoxazole ring

Nobuhiro Kanomata, Makoto Nitta, Kensuke Takahashi, Yutaka Takakura, Katsuhiro Saito

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Abstract

Novel norcaradiene-cycloheptatriene systems fused with arylisoxazoles were synthesized and their temperature dependent 1H nmr spectra were studied. While the fusion of isoxazole ring much shifted the norcaradiene-cycloheptatriene equilibrium to the side of norcaradiene form, the rapid isomerizations of the norcaradienes with their enantiomers were observed and their ΔGC{double barred pipe} values were obtained.

Original languageEnglish
Pages (from-to)3105-3109
Number of pages5
JournalHeterocycles
Volume26
Issue number12
Publication statusPublished - 1987 Dec 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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  • Cite this

    Kanomata, N., Nitta, M., Takahashi, K., Takakura, Y., & Saito, K. (1987). Synthesis and properties of norcaradiene-cycloheptatriene system fused with isoxazole ring. Heterocycles, 26(12), 3105-3109.